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A suicide enzyme catalyzes multiple reactions for biotin biosynthesis in cyanobacteria
Sakaki K, et al. Nat Chem Biol 2020. Among authors: Watanabe H. PMID 32042199
This enzyme catalyzes three reactions: formation of covalent linkage with AON to yield a BioU-DAN conjugate at the ε-amino group of Lys124 of BioU using NAD(P)H, carboxylation of the conjugate to form BioU-DAN-carbamic acid, and release of DAN-carbamic acid using NAD(P)(+). ...
This enzyme catalyzes three reactions: formation of covalent linkage with AON to yield a BioU-DAN conjugate at the ε-amino group of Lys124 o …
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