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Computational studies on biosynthetic carbocation rearrangements leading to sativene, cyclosativene, alpha-ylangene, and beta-ylangene.
Lodewyk MW, Gutta P, Tantillo DJ. Lodewyk MW, et al. J Org Chem. 2008 Sep 5;73(17):6570-9. doi: 10.1021/jo800868r. Epub 2008 Aug 6. J Org Chem. 2008. PMID: 18681400
In this paper, we describe theoretical studies, using gas-phase quantum chemical calculations, on carbocationic rearrangement pathways leading to the sesquiterpenes sativene, cyclosativene, alpha-ylangene, and beta-ylangene. For all four sesquiterpene natural produc …
In this paper, we describe theoretical studies, using gas-phase quantum chemical calculations, on carbocationic rearrangement pathways leadi …
Ylangene-type and nardosinane-type sesquiterpenoids from the soft corals Lemnalia flava and Paralemnalia thyrsoides.
Cheng SY, Lin EH, Huang JS, Wen ZH, Duh CY. Cheng SY, et al. Chem Pharm Bull (Tokyo). 2010 Mar;58(3):381-5. doi: 10.1248/cpb.58.381. Chem Pharm Bull (Tokyo). 2010. PMID: 20190445 Free article.
Chemical investigations of the Formosan soft coral Lemnalia flava have obtained a new ylangene-type sesquiterpenoid, (1S,2S,4R,6S,7R,8S)-4alpha-formyloxy-beta-ylangene (1), along with two known sesquiterpenoids, lemnalol (2) and isolemnalol (3). ...
Chemical investigations of the Formosan soft coral Lemnalia flava have obtained a new ylangene-type sesquiterpenoid, (1S,2S,4R,6S,7R,8S)-4al …
epi-Cubebanes from Solidago canadensis.
Kasali AA, Ekundayo O, Paul C, König WA. Kasali AA, et al. Phytochemistry. 2002 Apr;59(8):805-10. doi: 10.1016/s0031-9422(02)00006-7. Phytochemistry. 2002. PMID: 11937158
GC-MS of the essential oil prepared by hydrodistillation of the green parts of a specimen of Solidago canadensis collected near Katowice, Poland, revealed two new sesquiterpene hydrocarbons. Their EI mass spectra resembled the mass spectrum of beta-ylangene (1) but …
GC-MS of the essential oil prepared by hydrodistillation of the green parts of a specimen of Solidago canadensis collected near Katowice, Po …
(-)-Germacrene D receptor neurones in three species of heliothine moths: structure-activity relationships.
Stranden M, Liblikas I, König WA, Almaas TJ, Borg-Karlson AK, Mustaparta H. Stranden M, et al. J Comp Physiol A Neuroethol Sens Neural Behav Physiol. 2003 Jul;189(7):563-77. doi: 10.1007/s00359-003-0434-y. Epub 2003 Jun 25. J Comp Physiol A Neuroethol Sens Neural Behav Physiol. 2003. PMID: 12827423
The effect of (-)-germacrene D was about ten times stronger than that of the (+)-enantiomer, which again was about ten times stronger than that of (-)-alpha-ylangene. Weaker effects were obtained for (+)-beta-ylangene, (+)-alpha-copaene, beta-copaene and two unident …
The effect of (-)-germacrene D was about ten times stronger than that of the (+)-enantiomer, which again was about ten times stronger than t …
Male lures for mediterranean fruitfly (Ceratitis capitata wied.): Structural analogs of α-copaene.
Flath RA, Cunningham RT, Mon TR, John JO. Flath RA, et al. J Chem Ecol. 1994 Oct;20(10):2595-609. doi: 10.1007/BF02036194. J Chem Ecol. 1994. PMID: 24241834
The tested analogs fell into two groups, based on their levels of attraction: (+)-alpha-ylangene, (+)-beta-copaene, (+)-beta-ylangene, and (-)-alpha-copaene were found to be somewhat attractive, although much less so than (+)-alpha-copaene, while (+)-cyclosativene, …
The tested analogs fell into two groups, based on their levels of attraction: (+)-alpha-ylangene, (+)-beta-copaene, (+)-beta-ylang
Additional male mediterranean fruitfly (Ceratitis capitata wied.) Attractants from Angelica seed oil (Angelica archangelica L.).
Flath RA, Cunningham RT, Mon TR, John JO. Flath RA, et al. J Chem Ecol. 1994 Aug;20(8):1969-84. doi: 10.1007/BF02066237. J Chem Ecol. 1994. PMID: 24242723
Two sesquiterpene hydrocarbons, beta-copaene and beta-ylangene, were isolated from bioactive fractions of angelica seed oil and were shown by field bioassays to be attractive to the male Mediterranean fruit fly. Their relative attractiveness, compared with the(+)-an …
Two sesquiterpene hydrocarbons, beta-copaene and beta-ylangene, were isolated from bioactive fractions of angelica seed oil an …
[Sesquiterpene hydrocarbons from grapes (author's transl)].
Schreier P, Drawert F, Junker A. Schreier P, et al. Z Lebensm Unters Forsch. 1976;160(3):271-4. doi: 10.1007/BF01132291. Z Lebensm Unters Forsch. 1976. PMID: 983335 German.
After separation by column chromatography on silicagel and preparative gas chromatography 14 sesquiterpene hydrocarbons have been identified in aroma extracts from grapes by gas chromatography--mass spectrometry: alpha-copaene, beta-ylangene, beta-bourbonene, beta-c …
After separation by column chromatography on silicagel and preparative gas chromatography 14 sesquiterpene hydrocarbons have been identified …
The floral transcriptome of ylang ylang (Cananga odorata var. fruticosa) uncovers biosynthetic pathways for volatile organic compounds and a multifunctional and novel sesquiterpene synthase.
Jin J, Kim MJ, Dhandapani S, Tjhang JG, Yin JL, Wong L, Sarojam R, Chua NH, Jang IC. Jin J, et al. J Exp Bot. 2015 Jul;66(13):3959-75. doi: 10.1093/jxb/erv196. Epub 2015 May 8. J Exp Bot. 2015. PMID: 25956881 Free PMC article.
CoTPS3 catalysed the conversion of farnesyl pyrophosphate to alpha-bergamotene, whereas CoTPS2 was found to be a multifunctional and novel TPS that could catalyse the synthesis of three sesquiterpenes, beta-ylangene, beta-copaene, and beta-cubebene. Additionally, th …
CoTPS3 catalysed the conversion of farnesyl pyrophosphate to alpha-bergamotene, whereas CoTPS2 was found to be a multifunctional and novel T …
Antibacterial activity of Syzygium aromaticum seed: Studies on oxidative stress biomarkers and membrane permeability.
Ajiboye TO, Mohammed AO, Bello SA, Yusuf II, Ibitoye OB, Muritala HF, Onajobi IB. Ajiboye TO, et al. Microb Pathog. 2016 Jun;95:208-215. doi: 10.1016/j.micpath.2016.03.011. Epub 2016 Mar 31. Microb Pathog. 2016. PMID: 27038843
Syzygium aromaticum seeds contain eugenol acetate > beta-carophyllene > eugenin > eugenol > methyl salicylate > beta-humulene > rhamnatin > fernesol > alpha-copeane > beta-ylangene > kaempferol > cinnamic acid > oleanolic acid &gt …
Syzygium aromaticum seeds contain eugenol acetate > beta-carophyllene > eugenin > eugenol > methyl salicylate > beta-humulene …
Antibacterial Activities of Endophytic Fungi Isolated from Mentha cordifolia Leaves and Their Volatile Constituents.
Monggoot S, Burawat J, Pripdeevech P. Monggoot S, et al. Nat Prod Commun. 2016 Sep;11(9):1349-1351. Nat Prod Commun. 2016. PMID: 30807040
Twenty-one components were identified. 2-Phenylethanol (38.7%), E-ligustilide (12.4%), a-eudesmol (10.2%), beta-vetivone (4.6%), beta-ylangene (3.7%) and verbanol (3.4%) were the major components of the extract. ...
Twenty-one components were identified. 2-Phenylethanol (38.7%), E-ligustilide (12.4%), a-eudesmol (10.2%), beta-vetivone (4.6%), beta
12 results