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Enantioselective Reductive Cyclization of Alkynyl-Tethered Cyclohexadienones Catalyzed by Rhodium Complexes.
Wang YF, Wang F, Yang DD, Kittakoop P, Tan YX, Tian P. Wang YF, et al. Org Lett. 2024 Jul 12;26(27):5614-5619. doi: 10.1021/acs.orglett.4c01276. Epub 2024 Jul 2. Org Lett. 2024. PMID: 38953701
In this study, the enantioselective reductive cyclization of alkynyl-tethered cyclohexadienones (1,6-enynes) has been developed via a chiral pincer rhodium catalyst, affording cis-hydrobenzofurans and cis-hydroindoles with high enantioselectivities (90-99% ee). Furthermore …
In this study, the enantioselective reductive cyclization of alkynyl-tethered cyclohexadienones (1,6-enynes) has been developed via a chiral …
Rh(I)-Catalyzed Allenic Pauson-Khand Reaction to Access the Thapsigargin Core: Influence of Furan and Allenyl Chloroacetate Groups on Enantioselectivity.
Deihl ED, Jesikiewicz LT, Newman LJ, Liu P, Brummond KM. Deihl ED, et al. Org Lett. 2022 Feb 4;24(4):995-999. doi: 10.1021/acs.orglett.1c03951. Epub 2022 Jan 26. Org Lett. 2022. PMID: 35081313
Thapsigargin (Tg) is a potent SERCA pump inhibitor with the potential to treat cancer and COVID-19. We have extended the scope of the asymmetric allenic Pauson-Khand reaction to furan-tethered allene-ynes, a stereoconvergent transformation affording the 5,7,5-ring s …
Thapsigargin (Tg) is a potent SERCA pump inhibitor with the potential to treat cancer and COVID-19. We have extended the scope …
Noble Metal Organometallic Complexes Display Antiviral Activity against SARS-CoV-2.
Chuong C, DuChane CM, Webb EM, Rai P, Marano JM, Bernier CM, Merola JS, Weger-Lucarelli J. Chuong C, et al. Viruses. 2021 May 25;13(6):980. doi: 10.3390/v13060980. Viruses. 2021. PMID: 34070524 Free PMC article.
SARS-CoV-2 emerged in 2019 as a devastating viral pathogen with no available preventative or treatment to control what led to the current global pandemic. ...Our findings demonstrate that two pentamethylcyclopentadienyl (Cp*) rhodium piano stool comple …
SARS-CoV-2 emerged in 2019 as a devastating viral pathogen with no available preventative or treatment to control what …
Pt-, Rh-, Ru-, and Cu-Single-Wall Carbon Nanotubes Are Exceptional Candidates for Design of Anti-Viral Surfaces: A Theoretical Study.
Aasi A, Aghaei SM, Moore MD, Panchapakesan B. Aasi A, et al. Int J Mol Sci. 2020 Jul 23;21(15):5211. doi: 10.3390/ijms21155211. Int J Mol Sci. 2020. PMID: 32717853 Free PMC article.
As SARS-CoV-2 is spreading rapidly around the globe, adopting proper actions for confronting and protecting against this virus is an essential and unmet task. ...
As SARS-CoV-2 is spreading rapidly around the globe, adopting proper actions for confronting and protecting against thi …