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Tailor-Made Poly(vinylamine) via Purple LED-Activated RAFT Polymerization of N-vinylformamide.
Kurowska I, Dupre-Demorsy A, Balayssac S, Hennetier M, Ric A, Bourdon V, Ando T, Ajiro H, Coutelier O, Destarac M. Kurowska I, et al. Macromol Rapid Commun. 2023 Feb;44(4):e2200729. doi: 10.1002/marc.202200729. Epub 2022 Dec 13. Macromol Rapid Commun. 2023. PMID: 36443826
To demonstrate the potential of this approach, an original poly(N-vinylpyrrolidone)-b-poly(N-vinylformamide) (PVP-b-PNVF) diblock copolymer is synthesized and characterized by aqueous size-exclusion chromatography (SEC), asymmetric flow field-flow fractionation (A4F), and …
To demonstrate the potential of this approach, an original poly(N-vinylpyrrolidone)-b-poly(N-vinylformamide) (PVP-b-PNVF) diblock copolym …
Synthesis of Poly(N-vinylamide)s and Poly(vinylamine)s and Their Block Copolymers by Organotellurium-Mediated Radical Polymerization.
Fan W, Yamago S. Fan W, et al. Angew Chem Int Ed Engl. 2019 May 20;58(21):7113-7116. doi: 10.1002/anie.201902940. Epub 2019 Apr 12. Angew Chem Int Ed Engl. 2019. PMID: 30920088
Hydrolysis of the polymers, in particular PNVF, occurred quantitatively under mild reaction conditions, giving structurally controlled poly(vinylamine)s. Block copolymers containing poly(N-vinylamide) and poly(vinylamine) segments were also synthesized in a c …
Hydrolysis of the polymers, in particular PNVF, occurred quantitatively under mild reaction conditions, giving structurally controlled poly( …
Poly(vinylamine-co-N-isopropylacrylamide) linear polymer and hydrogels with tuned thermoresponsivity.
Fischer T, Demco DE, Fechete R, Möller M, Singh S. Fischer T, et al. Soft Matter. 2020 Jul 22;16(28):6549-6562. doi: 10.1039/d0sm00408a. Soft Matter. 2020. PMID: 32617537
To meet this challenge we copolymerize N-isopropylacrylamide (NIPAm) with N-vinylformamide (NVF) in different ratios with the formamide group being subsequently selectively hydrolyzed to the corresponding amine (VAm). The copolymers are crosslinked with phenylcarbonate tel …
To meet this challenge we copolymerize N-isopropylacrylamide (NIPAm) with N-vinylformamide (NVF) in different ratios with the formamide grou …
Study of cellulolytic enzyme immobilization on copolymers of N-vinylformamide.
Tąta A, Sokołowska K, Świder J, Konieczna-Molenda A, Proniewicz E, Witek E. Tąta A, et al. Spectrochim Acta A Mol Biomol Spectrosc. 2015;149:494-504. doi: 10.1016/j.saa.2015.04.112. Epub 2015 May 8. Spectrochim Acta A Mol Biomol Spectrosc. 2015. PMID: 25978017
The formamide groups in these carriers were hydrolyzed to amino groups, yielding three P(VAm-co-DVB) polymers with vinylamine units. Enzyme, cellulase (Novozym 476), was immobilized onto carriers with vinylamine (through glutaraldehyde) and vinylformamide groups (wi …
The formamide groups in these carriers were hydrolyzed to amino groups, yielding three P(VAm-co-DVB) polymers with vinylamine units. …
Self-Decontaminating Fibrous Materials Reactive toward Chemical Threats.
Bromberg L, Su X, Martis V, Zhang Y, Hatton TA. Bromberg L, et al. ACS Appl Mater Interfaces. 2016 Jul 13;8(27):17555-64. doi: 10.1021/acsami.6b05241. Epub 2016 Jun 27. ACS Appl Mater Interfaces. 2016. PMID: 27309383
Polymers that possess highly nucleophilic pyrrolidinopyridine (Pyr) and primary amino (vinylamine, VAm) groups were prepared by free-radical copolymerization of N,N-diallylpyridin-4-amine (DAAP) and N-vinylformamide (NVF) followed by acidic hydrolysis of NVF into VAm. The …
Polymers that possess highly nucleophilic pyrrolidinopyridine (Pyr) and primary amino (vinylamine, VAm) groups were prepared by free- …