The chlorate-iodine clock reaction

J Am Chem Soc. 2005 Dec 28;127(51):18022-3. doi: 10.1021/ja0570537.

Abstract

A clock reaction produced by mixing chlorate and iodine solutions in perchloric acid media is reported. This is the first example of a clock reaction using chlorate as a reagent. Increasing chlorate and acid concentration reduces the induction period. Changing the initial iodine concentration does not affect the length of the induction period. The discovery of this clock reaction opens the possibility that a new family of oscillation reactions can be built using chlorate as reagent.