1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(eta(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2'-1,3-dioxolan]-2-yloxy}benzene)chromium

Harinandini Paramahamsan; Anthony J Pearson; Nathalie M Pinkerton; A Alan Pinkerton

doi:10.1107/S0108270108004666

1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(eta(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2'-1,3-dioxolan]-2-yloxy}benzene)chromium

Acta Crystallogr C. 2008 Apr;64(Pt 4):m147-8. doi: 10.1107/S0108270108004666. Epub 2008 Mar 8.

Authors

Harinandini Paramahamsan¹, Anthony J Pearson, Nathalie M Pinkerton, A Alan Pinkerton

Affiliation

¹ Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106, USA.

Abstract

The tricarbonylchromium unit bound to the arene ring of the chiral title complex, [Cr(C(19)H(26)O(3))(CO)(3)], is rotated by ca 25 degrees in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.

Publication types

Research Support, N.I.H., Extramural

MeSH terms

Bridged Bicyclo Compounds / chemistry*
Chromium Compounds / chemistry*
Crystallography, X-Ray
Models, Molecular
Molecular Structure

Substances

Bridged Bicyclo Compounds
Chromium Compounds

Abstract

Publication types

MeSH terms

Substances

Grants and funding