Abstract
Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acid substrates has been achieved through the use of monoprotected chiral amino acid ligands. The absolute configuration of the resulting olefinated products is consistent with that of a proposed C-H insertion intermediate.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Aldehydes / chemical synthesis
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Aldehydes / chemistry
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Alkenes / chemical synthesis*
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Alkenes / chemistry
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Catalysis
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Crystallography, X-Ray
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Cyclization
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Diphenylacetic Acids / chemistry*
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Lactones / chemical synthesis
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Lactones / chemistry
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemistry*
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Palladium / chemistry*
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Stereoisomerism
Substances
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Aldehydes
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Alkenes
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Diphenylacetic Acids
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Lactones
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Organometallic Compounds
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Palladium