Manganese-Oxide-Based Electrode Materials for Energy Storage Applications: How Close Are We to the Theoretical Capacitance?

Abstract

Of the transition metals, Mn has the greatest number of different oxides, most of which have a special tunnel structure that enables bulk redox reactions. The high theoretical capacitance and capacity results from a greater number of accessible oxidation states than other transition metals, wide potential window, and the high natural abundance make MnO_x species promising electrode materials for energy storage applications. Although MnO_x electrode materials have been intensely studied over the past decade, their electrochemical performance is still insufficient for practical applications. Currently, there is a trade-off between specific capacitance and loading mass. MnO_x species have intrinsically poor electrical conductivity, and current structural designs are not sophisticated enough to accommodate enough redox-active sites. Recent studies have certainly made progress in increasing capacitance through making use of electrically conductive components and controlling the morphology of the MnO_x species to expose more surface area. To increase the capacitance of MnO_x electrodes to the largest extent without limiting loading mass, further structural design at the nanoscale and manipulation of the electrically conductive component are required. An ideal nanostructure is proposed to guide future research toward closing the gap between achieved and theoretical capacitance, without limiting the loading mass.

Keywords: energy storage; loading mass; manganese oxides; structural design; theoretical capacitance.