Multifunctional Polymolybdate-Based Metal-Organic Framework as an Efficient Catalyst for the CO2 Cycloaddition and as the Anode of a Lithium-Ion Battery

Yun-Shan Xue; Wei-Wei Cheng; Xi-Ming Luo; Jia-Peng Cao; Yan Xu

doi:10.1021/acs.inorgchem.9b01977

Multifunctional Polymolybdate-Based Metal-Organic Framework as an Efficient Catalyst for the CO₂ Cycloaddition and as the Anode of a Lithium-Ion Battery

Inorg Chem. 2019 Oct 7;58(19):13058-13065. doi: 10.1021/acs.inorgchem.9b01977. Epub 2019 Sep 18.

Authors

Yun-Shan Xue^{1

2}, Wei-Wei Cheng¹, Xi-Ming Luo¹, Jia-Peng Cao¹, Yan Xu¹

Affiliations

¹ College of Chemical Engineering , State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University , Nanjing 210009 , P. R. China.
² School of Chemistry and Environmental Engineering , Yancheng Teachers University , Yancheng , Jiangsu 224002 , P. R. China.

PMID: 31532643
DOI: 10.1021/acs.inorgchem.9b01977

Abstract

A three-dimensional polymolybdate-based metal-organic framework (POMOF) consisting of Zn-ε-Keggin unit and organic linker, {[PMo₈^VMo₄^VIO₃₇(OH)₃Zn₄][BPE]₂}·[BPE] (1), was successfully obtained by the hydrothermal method. Compound 1 is composed of Zn-ε-Keggin units and BPE ligands, featuring a fascinating 5-fold interpenetrating framework with dia topology. The catalytic performance of compound 1 was investigated, and experiments showed that 1 could effectively facilitate the cycloaddition reaction of CO₂ with epoxides as Lewis acid heterogeneous catalyst. Moreover, compound 1 also was studied as LIBs anode material, and it showed reversible capacity of 546 mA h g^-1 at 100th cycle.