Synthesis of TiO2/RGO with plasmonic Ag nanoparticles for highly efficient photoelectrocatalytic reduction of CO2 to methanol toward the removal of an organic pollutant from the atmosphere

Abstract

The synergistic photoelectrochemical (PEC) technology is a robust process for the conversion of CO₂ into fuels. However, designing a highly efficient UV-visible driven photoelectrocatalyst is still challenging. Herein, a plasmonic Ag NPs modified TiO₂/RGO photoelectrocatalyst (Ag-TiO₂/RGO) has been designed for the PEC CO₂ reduction into selective production of CH₃OH. HR-TEM analysis revealed that Ag and TiO₂ NPs with average sizes of 4 and 7 nm, respectively, were densely grown on the few-micron-sized 2D RGO nanosheets. The physicochemical analysis was used to determine the optical and textural properties of the Ag-TiO₂/RGO nanohybrids. Under VU-Vis light illumination, Ag-TiO₂/RGO photocathode possessed a current density of 23.5 mA cm^-2 and a lower electrode resistance value of 125 Ω in CO₂-saturated 1.0 M KOH-aqueous electrolyte solution. Catalytic studies showed that the Ag-TiO₂/RGO photocathode possessed a remarkable PEC CO₂ reduction activity and selective production of CH₃OH with a yield of 85 μmol L^-1 cm^-2, the quantum efficiency of 20% and Faradic efficiency of 60.5% at onset potential of -0.7 V. A plausible PEC CO₂ reduction mechanism over Ag-TiO₂/RGO photocathode is schematically demonstrated. The present work gives a new avenue to develop high-performance and stable photoelectrocatalyst for PEC CO₂ reduction towards sustainable liquid fuels production.

Keywords: CO(2) reduction; Heterogeneous electrocatalysts; Methanol; Photocathode; Plasmonics; Sustainable liquid fuels.