High-yield and large-scale synthesis are highly demanded for the studies of gold nanoclusters. We developed a "cluster from cluster" approach to assemble gold nanoclusters with preformed atomically precise Au13 precursors. This facile approach has proved to be very effective in the synthesis of the well-known magic cluster [Au25 (SR)18 ]- , which could prepare the target cluster in high yield (overall yield up to ≈100 %) at large scale (gram-scale based on gold). This method can be applied in the synthesis of 10 Au25 clusters with different R groups. This work presents an important approach that may be extended to high-yield and large-scale synthesis of other metal nanoclusters.
Keywords: S ligands; cluster compounds; facile synthesis; gold; large scale.
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