Decorated Mn-ferrite nanoparticle@Zn-Al layered double hydroxide@Cellulose@ activated biochar nanocomposite for efficient remediation of methylene blue and mercury (II)

Abstract

An innovative magnetic nanocomposite was designed and fabricated by the functionalization and support of magnetic Mn-ferrite nanoparticle (MnFe₂O₄) with layered double hydroxide (Zn-Al LDHs) on cellulose and activated grapes stalks-derived biochar (AGB) (MnFe₂O₄@Zn-Al LDHs@Cel@AGB), to incorporate active functionalities and fantastic features with the aim to explore its feasibility for removal of harmful cationic species as methylene blue dye (MB) and mercury ions from wastewater. Structural, composition, morphological, surface area, adsorption performance of the fabricated nanocomposite toward both MB and Hg(II) and reusability were also investigated. The results referred that 10 mg ofthe nanocomposite exhibited 97.4% and 84.0 % removal efficiency of 10mgL^-1 MB dye and 0.1 mol L^-1 Hg(II) at 25 and 30 min contact times, respectively. Adsorption isotherms and kinetics of the two pollutants (MB and Hg(II)) were both governed by the pseudo-second-order equation with possible participation of intraparticle diffusion mechanism.

Keywords: Activated grapes stalks-derived biochar; Cellulose, Mn-ferrite nanoparticle; Layered double hydroxide; Methylene blue dye and Hg(II) removal.