Heterostructured CoS2/CuCo2S4@N-doped carbon hollow sphere for potassium-ion batteries

Guoquan Suo; Syed Musab Ahmed; Yan Cheng; Jiaqi Zhang; Zongyou Li; Xiaojiang Hou; Yanling Yang; Xiaohui Ye; Lei Feng; Li Zhang; Qiyao Yu

doi:10.1016/j.jcis.2021.09.137

Heterostructured CoS₂/CuCo₂S₄@N-doped carbon hollow sphere for potassium-ion batteries

J Colloid Interface Sci. 2022 Feb 15;608(Pt 1):275-283. doi: 10.1016/j.jcis.2021.09.137. Epub 2021 Sep 29.

Authors

Guoquan Suo¹, Syed Musab Ahmed², Yan Cheng², Jiaqi Zhang², Zongyou Li³, Xiaojiang Hou², Yanling Yang², Xiaohui Ye², Lei Feng², Li Zhang², Qiyao Yu⁴

Affiliations

¹ School of Material Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, China. Electronic address: suoguoquan@sust.edu.cn.
² School of Material Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, China.
³ Institute of Advanced Structure Technology, Beijing Institute of Technology, Beijing 100081, China.
⁴ Institute of Advanced Structure Technology, Beijing Institute of Technology, Beijing 100081, China. Electronic address: qiyaoyu@bit.edu.cn.

PMID: 34626974
DOI: 10.1016/j.jcis.2021.09.137

Abstract

Potassium ions batteries (PIBs) have been regarded as a promising choice for electrical energy storage technology due to the wide distribution of potassium resources. However, developing low-cost and robust earth-rich anode materials is still a major challenge for the practical and scalable usage of PIBs. Herein, for the first time, we developed nitrogen doped carbon coating CoS₂/CuCo₂S₄ heterostructure (CoS₂/CuCo₂S₄@NCs) hollow spheres and evaluated as anode for PIBs. The CoS₂ and CuCo₂S₄ heterostructure interface could generate a built-in electric field, which can fasten electrons transportation. The nanostructures could shorten the diffusion length of K⁺ and provide large surface area to contact with electrolytes. Furthermore, the inner hollow sphere morphology along with the carbon layer could accommodate the volume expansion during cycling. What's more, the N-doped carbon could increase the conductivity of the anodes. Benefitting from the above features, the CoS₂/CuCo₂S₄@NCs displays an outstanding rate capability (309 mAh g^-1 at 500 mA g^-1 after 250 cycles) and a long-term cycling life (112 mAh g^-1 at 1000 mA g^-1 after 1000 cycles) in ether-based electrolyte. Conversion reaction mechanism in CoS₂/CuCo₂S₄@NCs anode is also revealed through ex situ XRD characterizations. This work provides a practical direction for investigating metal sulfides as anode for PIBs.

Keywords: Anode materials; CoS(2); CuCo(2)S(4); Energy storage; Potassium ions batteries.