Silver nanowire (Ag NW)-based transparent electrodes (TEs) are promising alternatives to indium tin oxide (ITO) for next-generation flexible optoelectronic devices. Although many different constructs of Ag NW networks and post-treatment methods have been developed for TE applications, trade-offs between optical and electrical performance still remain. Herein, aided by electrohydrodynamic (EHD) printing, we present a cost-effective strategy to fabricate aligned Ag NW microgrids in a large area with excellent uniformity, resulting in superior optoelectronic properties. Guided by the percolation theory and simulation, we demonstrated that by confining aligned Ag NWs into a microgrid arrangement, the percolation threshold can be reduced significantly and adequate electrical conducting pathways can be achieved with an optimized combination of sheet resistance and optical transparency, which surpass conventional random Ag NW networks and random aligned Ag NW networks. The resulting TEs exhibit an ultrahigh transmittance of 99.1% at a sheet resistance of 91 Ω sq-1 with extremely low nanowire usage, an areal mass density of only 8.3 mg m-2, and uniform spatial distribution. Based on this TE design, we demonstrated transparent heaters exhibiting rapid thermal response and superior uniformity in heat generation. Using UV-curable epoxy, highly flexible Ag NW-embedded TEs were fabricated with superior mechanical stabilities and low surface roughness of 2.6 nm. Bendable organic light-emitting diodes (OLEDs) are directly fabricated on these flexible Ag NW electrodes, with higher current efficiency (27.7 cd A-1) than ITO devices (24.8 cd A-1).
Keywords: aligned Ag NW microgrids; electrohydrodynamic printing; flexible transparent electrode; organic light-emitting diode; transparent heater.