Two-dimensional (2D) materials have emerged as prospective candidates for electronics and optoelectronics applications as they can be easily fabricated through liquid exfoliation and used to fabricate various structures by further subsequent processing methods in addition to their extraordinary and unique optoelectronic properties. Herein, the Ti3 C2 Tx /ZIS heterostructure with nanometer-thick Ti3 C2 Tx -MXene and ZnIn2 S4 (ZIS) films is fabricated by successive interfacial assembly of liquid exfoliated 2D MXene and ZnIn2 S4 nanoflakes. Benefiting from the superior light-harvesting capability and low dark current of ZnIn2 S4 , the limited absorbance, large scattering coefficient, and high dark current disadvantages of MXene are ameliorated. Meanwhile, the separation and transport of photogenerated carriers in ZnIn2 S4 are improved due to the excellent electrical conductivity of Ti3 C2 Tx nanoflakes. As a result, the as-prepared Ti3 C2 Tx /ZIS heterostructure photodetector has excellent optoelectronic characteristics in terms of a high responsivity of 1.04 mA W-1 , a large specific detectivity up to 1 × 1011 Jones, a huge on/off ratio at around 105 , and an ultralow dark current at ≈10-12 A. This work demonstrates a convenient method to construct heterostructured photodetectors by liquid exfoliated 2D nanoflakes, the as-fabricated Ti3 C2 Tx /ZIS heterostructured photodetectors show promising application potential for low-cost, reliable, and high-performance photodetectors.
Keywords: MXene; ZnIn2S4; interfacial assembly; liquid exfoliation; photodetector; two-dimensional heterostructure.
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