Potassium-ion batteries (PIBs) with conventional organic-based flammable electrolytes suffer from serious safety issues with a high risk of ignition and burning especially under harsh conditions, which significantly limits their widespread applications. Flame-retardant electrolytes (FREs) are considered as one of the most effective strategies to address these safety issues. Therefore, it's much necessary to summarize the challenges, recent progress, and design principles of flame-retardant nonaqueous electrolytes for PIBs to guide their development and future applications. In this review, an in-depth introduction and explanation of the origins of electrolyte flammability are first presented. Particularly, the state-of-the-art design principles of FREs for PIBs are extensively summarized and emphasized, including the electrolyte flame-retardant solvents/additives, highly concentrated electrolytes (HCEs), localized high-concentration electrolytes (LHCEs), ionic liquids-based electrolytes and solid-state electrolytes. Moreover, the advantages and drawbacks of each approach are systematically presented and discussed, following by proposed perspectives to guide the rational development of next-generation high-safety PIBs for practical applications.
Keywords: flame-retardant mechanisms; nonaqueous electrolytes; potassium-ion batteries; safety issues; solid electrolyte interphase.
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