Tunable emission from H-type supramolecular polymers in optical nanocavities

Giulia Lavarda; Anton M Berghuis; Kripa Joseph; Joost J B van der Tol; Shunsuke Murai; Jaime Gómez Rivas; E W Meijer

doi:10.1039/d3cc05877h

Tunable emission from H-type supramolecular polymers in optical nanocavities

Chem Commun (Camb). 2024 Mar 5;60(20):2812-2815. doi: 10.1039/d3cc05877h.

Authors

Giulia Lavarda¹, Anton M Berghuis², Kripa Joseph¹, Joost J B van der Tol¹, Shunsuke Murai³, Jaime Gómez Rivas², E W Meijer¹

Affiliations

¹ Institute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, Eindhoven 5600 MB, The Netherlands. g.lavarda@tue.nl.
² Eindhoven Hendrik Casimir Institute and Institute for Complex Molecular Systems, Eindhoven University of Technology, Eindhoven 5600 MB, The Netherlands.
³ Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo, Kyoto 6158510, Japan.

Abstract

H-type supramolecular polymers with preferred helicity and highly efficient emission have been prepared from the self-assembly of chiral tetraphenylene-based monomers. Implementation of the one-dimensional fibers into dielectric nanoparticle arrays allows for a significant reshaping of fluorescence due to weak light-matter coupling.