Effects of Miscut on Step Instabilities in Homo-Epitaxially Grown GaN

Nanomaterials (Basel). 2024 Apr 25;14(9):748. doi: 10.3390/nano14090748.

Abstract

The rough morphology at the growth surface results in the non-uniform distribution of indium composition, intentionally or unintentionally doped impurity, and thus impacts the performance of GaN-based optoelectronic and vertical power electronic devices. We observed the morphologies of unintentionally doped GaN homo-epitaxially grown via MOCVD and identified the relations between rough surfaces and the miscut angle and direction of the substrate. The growth kinetics under the effect of the Ehrlich-Schwoebel barrier were studied, and it was found that asymmetric step motions in samples with a large miscut angle or those grown at high temperature were the causes of step-bunching. Meandering steps were believed to be caused by surface free energy minimization for steps with wide terraces or deviating from the [11¯00] m-direction.

Keywords: AFM; Ehrlich–Schwoebel (E-S) barrier; GaN; MOCVD; miscut; step bunching; step meandering.