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. 2002 Feb 6;124(5):773-5.
doi: 10.1021/ja016585u.

Biomimetic Synthesis of (-)-Longithorone A

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Biomimetic Synthesis of (-)-Longithorone A

Mark E Layton et al. J Am Chem Soc. .

Abstract

An enantioseletive, biomimetic synthesis of (-)-longithorone A has been achieved using an intermolecular/transannular Diels-Alder sequence which provides some support for the proposed biosynthesis. The cycloaddition precursors were two [12]-paracyclophanes that were constructed with atropisomer control during ene-yne metathesis macrocyclizations.

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