Shell-driven magnetic stability in core-shell nanoparticles

Phys Rev Lett. 2006 Oct 13;97(15):157203. doi: 10.1103/PhysRevLett.97.157203. Epub 2006 Oct 13.

Abstract

The magnetic properties of ferromagnetic-antiferromagnetic Co-CoO core-shell nanoparticles are investigated as a function of the in-plane coverage density from 3.5% to 15%. The superparamagnetic blocking temperature, the coercivity, and the bias field radically increase with increasing coverage. This behavior cannot be attributed to the overall interactions between cores. Rather, it can be semiquantitatively understood by assuming that the shells of isolated core-shell nanoparticles have strongly degraded magnetic properties, which are rapidly recovered as nanoparticles come into contact.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cobalt / chemistry*
  • Magnetics*
  • Metal Nanoparticles / chemistry*
  • Oxides / chemistry*
  • Temperature

Substances

  • Oxides
  • Cobalt
  • cobalt oxide