Unusual noncovalent interaction between the chelated Cu(II) ion and the pi bond in the vitamin B(13) complex, cis-diammine(orotato)copper(II): theoretical and vibrational spectroscopy studies.
Helios K, Wysokiński R, Zierkiewicz W, Proniewicz LM, Michalska D.
Helios K, et al. Among authors: michalska d.
J Phys Chem B. 2009 Jun 11;113(23):8158-69. doi: 10.1021/jp901912v.
J Phys Chem B. 2009.
PMID: 19453135
The crystal structure of the Cu(II) complex with Vitamin B(13) (orotic acid), cis-[Cu(oro)(NH(3))(2)] has revealed the presence of unusual, noncovalent pi-type interaction between the chelated Cu(II) ion and the C horizontal lineC bond of the uracilate ring [Michalska et a …
The crystal structure of the Cu(II) complex with Vitamin B(13) (orotic acid), cis-[Cu(oro)(NH(3))(2)] has revealed the presence of unusual, …