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Industrial Ziegler-type hydrogenation catalysts made from Co(neodecanoate)2 or Ni(2-ethylhexanoate)2 and AlEt3: evidence for nanoclusters and sub-nanocluster or larger Ziegler-nanocluster based catalysis.
Alley WM, Hamdemir IK, Wang Q, Frenkel AI, Li L, Yang JC, Menard LD, Nuzzo RG, Özkar S, Yih KH, Johnson KA, Finke RG. Alley WM, et al. Among authors: hamdemir ik. Langmuir. 2011 May 17;27(10):6279-94. doi: 10.1021/la200053f. Epub 2011 Apr 11. Langmuir. 2011. PMID: 21480617
Iridium Ziegler-type hydrogenation catalysts made from [(1,5-COD)Ir(mu-O2C8H15)](2) and AlEt3: spectroscopic and kinetic evidence for the Ir(n) species present and for nanoparticles as the fastest catalyst.
Alley WM, Hamdemir IK, Wang Q, Frenkel AI, Li L, Yang JC, Menard LD, Nuzzo RG, Ozkar S, Johnson KA, Finke RG. Alley WM, et al. Among authors: hamdemir ik. Inorg Chem. 2010 Sep 6;49(17):8131-47. doi: 10.1021/ic101237c. Inorg Chem. 2010. PMID: 20681520