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An unusual dinuclear ruthenium(III) complex with a conjugated bridging ligand derived from cleavage of a 1,4-dihydro-1,2,4,5-tetrazine ring. Synthesis, structure, and UV-vis-NIR spectroelectrochemical characterization of a five-membered redox chain incorporating two mixed-valence states.
Patra S, Miller TA, Sarkar B, Niemeyer M, Ward MD, Lahiri GK. Patra S, et al. Among authors: lahiri gk. Inorg Chem. 2003 Jul 28;42(15):4707-13. doi: 10.1021/ic034131n. Inorg Chem. 2003. PMID: 12870962
Isovalent and mixed-valent diruthenium complexes [(acac)2RuII (-bpytz)RuII(acac)2] and [(acac)2RuII(-bpytz)RuIII(acac)2](ClO4) (acac = acetylacetonate and bpytz = 3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): synthesis, spectroelectrochemical, and epr investigation.
Patra S, Sarkar B, Ghumaan S, Fiedler J, Kaim W, Lahiri GK. Patra S, et al. Among authors: lahiri gk. Inorg Chem. 2004 Sep 20;43(19):6108-13. doi: 10.1021/ic049346r. Inorg Chem. 2004. PMID: 15360263
3,6-bis(2'-pyridyl)pyridazine (L) and its deprotonated form (L - H+)- as ligands for {(acac)2Ru(n+)} or {(bpy)2Ru(m+)}: investigation of mixed valency in [{(acac)2Ru}2(mu-L - H+)]0 and [{(bpy)2Ru}2(mu-L - H+)]4+ by spectroelectrochemistry and EPR.
Ghumaan S, Sarkar B, Patra S, Parimal K, van Slageren J, Fiedler J, Kaim W, Lahiri GK. Ghumaan S, et al. Among authors: lahiri gk. Dalton Trans. 2005 Feb 21;(4):706-12. doi: 10.1039/b417530a. Epub 2005 Jan 17. Dalton Trans. 2005. PMID: 15702181
Isomeric ruthenium terpyridine complexes [Ru(trpy)(L)Cl]n+ containing the unsymmetrically bidentate acceptor L=3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine. Synthesis, structures, electrochemistry, spectroscopy and DFT calculations.
Patra S, Sarkar B, Ghumaan S, Patil MP, Mobin SM, Sunoj RB, Kaim W, Lahiri GK. Patra S, et al. Among authors: lahiri gk. Dalton Trans. 2005 Apr 7;(7):1188-94. doi: 10.1039/b500152h. Epub 2005 Feb 24. Dalton Trans. 2005. PMID: 15782253
176 results