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Efficient asymmetric synthesis of P-chiral phosphine oxides via properly designed and activated benzoxazaphosphinine-2-oxide agents.
Han ZS, Goyal N, Herbage MA, Sieber JD, Qu B, Xu Y, Li Z, Reeves JT, Desrosiers JN, Ma S, Grinberg N, Lee H, Mangunuru HP, Zhang Y, Krishnamurthy D, Lu BZ, Song JJ, Wang G, Senanayake CH. Han ZS, et al. Among authors: herbage ma. J Am Chem Soc. 2013 Feb 20;135(7):2474-7. doi: 10.1021/ja312352p. Epub 2013 Feb 6. J Am Chem Soc. 2013. PMID: 23369026
Diastereoselective Synthesis of α-Quaternary Aziridine-2-carboxylates via Aza-Corey-Chaykovsky Aziridination of N-tert-Butanesulfinyl Ketimino Esters.
Marsini MA, Reeves JT, Desrosiers JN, Herbage MA, Savoie J, Li Z, Fandrick KR, Sader CA, McKibben B, Gao DA, Cui J, Gonnella NC, Lee H, Wei X, Roschangar F, Lu BZ, Senanayake CH. Marsini MA, et al. Among authors: herbage ma. Org Lett. 2015 Nov 20;17(22):5614-7. doi: 10.1021/acs.orglett.5b02838. Epub 2015 Nov 11. Org Lett. 2015. PMID: 26558319
Design and synthesis of chiral oxathiozinone scaffolds: efficient synthesis of hindered enantiopure sulfinamides and sulfinyl ketimines.
Han ZS, Herbage MA, Mangunuru HP, Xu Y, Zhang L, Reeves JT, Sieber JD, Li Z, DeCroos P, Zhang Y, Li G, Li N, Ma S, Grinberg N, Wang X, Goyal N, Krishnamurthy D, Lu B, Song JJ, Wang G, Senanayake CH. Han ZS, et al. Among authors: herbage ma. Angew Chem Int Ed Engl. 2013 Jun 24;52(26):6713-7. doi: 10.1002/anie.201301676. Epub 2013 May 15. Angew Chem Int Ed Engl. 2013. PMID: 23677810 No abstract available.
Remarkable enhancement of enantioselectivity in the asymmetric conjugate addition of dimethylzinc to (Z)-nitroalkenes with a catalytic [(MeCN)₄Cu]PF₆-Hoveyda ligand complex.
Zeng X, Gao JJ, Song JJ, Ma S, Desrosiers JN, Mulder JA, Rodriguez S, Herbage MA, Haddad N, Qu B, Fandrick KR, Grinberg N, Lee H, Wei X, Yee NK, Senanayake CH. Zeng X, et al. Among authors: herbage ma. Angew Chem Int Ed Engl. 2014 Nov 3;53(45):12153-7. doi: 10.1002/anie.201406247. Epub 2014 Sep 15. Angew Chem Int Ed Engl. 2014. PMID: 25225113
Synthesis and applications of tert-butanesulfinamide.
Robak MT, Herbage MA, Ellman JA. Robak MT, et al. Among authors: herbage ma. Chem Rev. 2010 Jun 9;110(6):3600-740. doi: 10.1021/cr900382t. Chem Rev. 2010. PMID: 20420386 Review. No abstract available.