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Nuclear Resonance Vibrational Spectroscopy Definition of O2 Intermediates in an Extradiol Dioxygenase: Correlation to Crystallography and Reactivity.
Sutherlin KD, Wasada-Tsutsui Y, Mbughuni MM, Rogers MS, Park K, Liu LV, Kwak Y, Srnec M, Böttger LH, Frenette M, Yoda Y, Kobayashi Y, Kurokuzu M, Saito M, Seto M, Hu M, Zhao J, Alp EE, Lipscomb JD, Solomon EI. Sutherlin KD, et al. Among authors: srnec m. J Am Chem Soc. 2018 Dec 5;140(48):16495-16513. doi: 10.1021/jacs.8b06517. Epub 2018 Nov 26. J Am Chem Soc. 2018. PMID: 30418018 Free PMC article.
Electronic Structure of the Ferryl Intermediate in the α-Ketoglutarate Dependent Non-Heme Iron Halogenase SyrB2: Contributions to H Atom Abstraction Reactivity.
Srnec M, Wong SD, Matthews ML, Krebs C, Bollinger JM Jr, Solomon EI. Srnec M, et al. J Am Chem Soc. 2016 Apr 20;138(15):5110-22. doi: 10.1021/jacs.6b01151. Epub 2016 Apr 12. J Am Chem Soc. 2016. PMID: 27021969 Free PMC article.
The VT MCD spectra of the enzymatic S = 2 Fe(IV)O intermediate with Br(-) ligation contain information-rich features that largely parallel the corresponding spectra of the S = 2 model complex (TMG3tren)Fe(IV)O (Srnec, M.; Wong, S. D.; England, J; Que, L; Solomon, E. …
The VT MCD spectra of the enzymatic S = 2 Fe(IV)O intermediate with Br(-) ligation contain information-rich features that largely parallel t …
48 results