Positive shift in corrole redox potentials leveraged by modest β-CF3-substitution helps achieve efficient photocatalytic C-H bond functionalization by group 13 complexes.
Zhan X, Yadav P, Diskin-Posner Y, Fridman N, Sundararajan M, Ullah Z, Chen QC, Shimon LJW, Mahammed A, Churchill DG, Baik MH, Gross Z.
Zhan X, et al.
Dalton Trans. 2019 Aug 28;48(32):12279-12286. doi: 10.1039/c9dt02150g. Epub 2019 Jul 25.
Dalton Trans. 2019.
PMID: 31342035
As seen previously, -CF(3) group substitution leads to red shifts in both the absorption and emission spectra compared to their unsubstituted counterparts (X. Zhan, et al., Inorg. Chem., 2019, 58, 6184-6198). All CF(3)-substituted corrole complexes showed strong flu …
As seen previously, -CF(3) group substitution leads to red shifts in both the absorption and emission spectra compared to their unsubstitute …