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Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: exploratory syntheses of complexes of Cu, Fe, and Li.
Dalton Trans. 2024 May 21;53(20):8642-8656. doi: 10.1039/d4dt00749b.
Dalton Trans. 2024.
PMID: 38695637
Evolution of a 'privileged' P-alkene ligand: added planar chirality beats BINOL axial chirality in catalytic asymmetric C-C bond formation.
Leinauer L, Parla G, Messelbeger J, Herrera A, Heinemann FW, Langer J, Chuchelkin I, Grasruck A, Frieß S, Chelouan A, Gavrilov K, Dorta R.
Leinauer L, et al. Among authors: grasruck a.
Chem Commun (Camb). 2023 Dec 5;59(97):14451-14454. doi: 10.1039/d3cc04972h.
Chem Commun (Camb). 2023.
PMID: 37982441
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Stereochemical Stability of Planar-Chiral Benzazepine Tricyclics: Inversion Energies of P- and S-Alkene Ligands.
Calderón JC, Herrera A, Heinemann FW, Langer J, Linden A, Chelouan A, Grasruck A, Añez R, Clark T, Dorta R.
Calderón JC, et al. Among authors: grasruck a.
J Org Chem. 2023 Dec 1;88(23):16144-16154. doi: 10.1021/acs.joc.3c01447. Epub 2023 Nov 9.
J Org Chem. 2023.
PMID: 37944159
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Trapping of soluble, KCl-stabilized Cu(I) hydrides with CO2 gives crystalline formates.
Grasruck A, Parla G, Lou L, Langer J, Neiß C, Herrera A, Frieß S, Görling A, Schmid G, Dorta R.
Grasruck A, et al.
Chem Commun (Camb). 2023 Nov 21;59(93):13879-13882. doi: 10.1039/d3cc03033d.
Chem Commun (Camb). 2023.
PMID: 37933531
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Ir(IV) Sulfoxide-Pincer Complexes by Three-Electron Oxidative Additions of Br2 and I2. Unprecedented Trap-Free Reductive Elimination of I2 from a formal d5 Metal.
Frieß S, Benyak A, Herrera A, Escalona AM, Heinemann FW, Langer J, Fehn D, Pividori D, Grasruck A, Munz D, Meyer K, Dorta R.
Frieß S, et al. Among authors: grasruck a.
Inorg Chem. 2022 Jan 24;61(3):1236-1248. doi: 10.1021/acs.inorgchem.1c02956. Epub 2022 Jan 6.
Inorg Chem. 2022.
PMID: 34990121
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