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Unusual oxidative chemistry of N(omega)-hydroxyarginine and N-hydroxyguanidine catalyzed at an engineered cavity in a heme peroxidase.
Hirst J, Goodin DB. Hirst J, et al. J Biol Chem. 2000 Mar 24;275(12):8582-91. doi: 10.1074/jbc.275.12.8582. J Biol Chem. 2000. PMID: 10722697 Free article.
Mass spectrometry of the derivatized NHA products identified the yellow species as N-nitrosoarginine. We suggest that a nitrosylating agent, possibly derived from HNO, is produced by the oxidation of one molecule of substrate. ...
Mass spectrometry of the derivatized NHA products identified the yellow species as N-nitrosoarginine. We suggest that a nitros …
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