Thermally Stable Terbium(II) and Dysprosium(II) Bis-amidinate Complexes.
Jin PB, Luo QC, Gransbury GK, Vitorica-Yrezabal IJ, Hajdu T, Strashnov I, McInnes EJL, Winpenny REP, Chilton NF, Mills DP, Zheng YZ.
Jin PB, et al.
J Am Chem Soc. 2023 Dec 27;145(51):27993-28009. doi: 10.1021/jacs.3c07978. Epub 2023 Nov 24.
J Am Chem Soc. 2023.
PMID: 37997752
Free PMC article.
These data consistently show that [Ln(Piso)(2)] formally exhibit Ln(II) centers with 4f(n)5d(z2)(1) (Ln = Tb, n = 8; Dy, n = 9) valence electron configurations. We show that simple assignments of the f-d coupling to either L-S or J-s schemes are an oversimplificatio …
These data consistently show that [Ln(Piso)(2)] formally exhibit Ln(II) centers with 4f(n)5d(z2)(1) (Ln = Tb, n = 8; Dy, n = 9) valen …