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Criteria for the elucidation of the pseudopericyclic character of the cyclization of (Z)-1,2,4,6-heptatetraene and its heterosubstituted analogues: magnetic properties and natural bond orbital analysis.
Chemistry. 2003 Apr 14;9(8):1837-43. doi: 10.1002/chem.200390211.
Chemistry. 2003.
PMID: 12698442
The electrocyclization of heterosubstituted derivatives of (Z)-1,2,4,6-heptatetraene, (2Z)-2,4,5-hexatrien-1-imine and (2Z)-2,4,5-hexatrienal exhibit some features which suggest a pseudopericyclic mechanism. In order to examine this, a comprehensive st …
The electrocyclization of heterosubstituted derivatives of (Z)-1,2,4,6-heptatetraene, (2Z)-2,4,5-hexatrien-1-imine and …
Study of the Electrocyclization of (Z)-Hexa-1,3,5-triene and Its Heterosubstituted Analogues Based on Ab Initio and DFT Calculations.
Rodríguez-Otero J.
Rodríguez-Otero J.
J Org Chem. 1999 Sep 3;64(18):6842-6848. doi: 10.1021/jo990881w.
J Org Chem. 1999.
PMID: 11674694
A comprehensive theoretical study of the electrocyclization of (Z)-hexa-1,3,5-triene and its heterosubstituted analogues (E,Z)-[(2Z)-2,4-pentadienylidene]amine and (2Z)-2,4-pentadienal to 1,3-cyclohexadiene, 1,2-dihydropyridine, an …
A comprehensive theoretical study of the electrocyclization of (Z)-hexa-1,3,5-triene and its heterosubstituted analogues (E,Z) …
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