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Catalytic Hydrogenation/Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran.
Mäki-Arvela P, Ruiz D, Murzin DY. Mäki-Arvela P, et al. ChemSusChem. 2021 Jan 7;14(1):150-168. doi: 10.1002/cssc.202001927. Epub 2020 Oct 5. ChemSusChem. 2021. PMID: 32940953 Review.
The desired catalyst should have relatively high metal dispersion and some acidity to facilitate both hydrogenation and hydrogenolysis. However, overhydrogenation and overhydrogenolysis forming 2,5-dimethyltetrahydrofuran and methylfuran, respectively, should …
The desired catalyst should have relatively high metal dispersion and some acidity to facilitate both hydrogenation and hydrogenolysis. Howe …
Hydrodeoxygenation of 2,5-dimethyltetrahydrofuran over bifunctional Pt-Cs(2.5)H(0.5)PW(12)O(40) catalyst in the gas phase: enhancing effect of gold.
Althikrallah H, Kozhevnikova EF, Kozhevnikov IV. Althikrallah H, et al. RSC Adv. 2022 Jan 14;12(4):2287-2291. doi: 10.1039/d1ra09105k. eCollection 2022 Jan 12. RSC Adv. 2022. PMID: 35425256 Free PMC article.
2,5-Dimethyltetrahydrofuran (DMTHF) is deoxygenated to n-hexane with >99% selectivity at mild conditions (90 C, 1 bar H(2) pressure, fixed-bed reactor) in the presence of the bifunctional metal-acid catalyst Pt-CsPW comprising Pt and Cs(2.5)H(0.5)PW(12)O(4
2,5-Dimethyltetrahydrofuran (DMTHF) is deoxygenated to n-hexane with >99% selectivity at mild conditions (90 C, 1 ba
Recent advances in catalytic synthesis of 2,5-furandimethanol from 5-hydroxymethylfurfural and carbohydrates.
Du Z, Yang D, Cao Q, Dai J, Yang R, Gu X, Li F. Du Z, et al. Bioresour Bioprocess. 2023 Aug 19;10(1):52. doi: 10.1186/s40643-023-00676-x. Bioresour Bioprocess. 2023. PMID: 38647628 Free PMC article. Review.
Some useful compounds, such as 2,5-furandimethanol (FDM), 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTHF), have been synthesized by reduction of HMF. ...
Some useful compounds, such as 2,5-furandimethanol (FDM), 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTH …
Atmospheric Chemistry of Tetrahydrofuran, 2-Methyltetrahydrofuran, and 2,5-Dimethyltetrahydrofuran: Kinetics of Reactions with Chlorine Atoms, OD Radicals, and Ozone.
Andersen C, Nielsen OJ, Østerstrøm FF, Ausmeel S, Nilsson EJ, Sulbaek Andersen MP. Andersen C, et al. J Phys Chem A. 2016 Sep 22;120(37):7320-6. doi: 10.1021/acs.jpca.6b06618. Epub 2016 Sep 7. J Phys Chem A. 2016. PMID: 27556743
FTIR smog chamber techniques were used to study the kinetics of the gas-phase reactions of Cl atoms, OD radicals, and O3 with the five-membered ring-structured compounds tetrahydrofuran (C4H8O, THF), 2-methyltetrahydrofuran (CH3C4H7O, 2-MTHF), 2,5-dimethyltetrahy
FTIR smog chamber techniques were used to study the kinetics of the gas-phase reactions of Cl atoms, OD radicals, and O3 with the five-membe …
Kinetics and thermochemistry of 2,5-dimethyltetrahydrofuran and related oxolanes: next next-generation biofuels.
Simmie JM. Simmie JM. J Phys Chem A. 2012 May 10;116(18):4528-38. doi: 10.1021/jp301870w. Epub 2012 Apr 26. J Phys Chem A. 2012. PMID: 22494635
The enthalpies of formation, entropies, specific heats at constant pressure, enthalpy functions, and all carbon-hydrogen and carbon-methyl bond dissociation energies have been computed using high-level methods for the cyclic ethers (oxolanes) tetrahydrofuran, 2-methyltetrahydrofu …
The enthalpies of formation, entropies, specific heats at constant pressure, enthalpy functions, and all carbon-hydrogen and carbon-methyl b …
Tailoring the catalytic performance of Cu/SiO2 for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to renewable fuels.
Jia H, Lv Q, Xia Q, Hu W, Wang Y. Jia H, et al. Front Chem. 2022 Aug 22;10:979353. doi: 10.3389/fchem.2022.979353. eCollection 2022. Front Chem. 2022. PMID: 36072701 Free PMC article.
Efficient conversion of biomass-derived 5-hydroxymethylfurfural (HMF) to renewable fuels such as 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTHF) is of significance for sustainable energy supply. ...
Efficient conversion of biomass-derived 5-hydroxymethylfurfural (HMF) to renewable fuels such as 2,5-dimethylfuran (DMF) and 2,5
Mechanistic study of a one-step catalytic conversion of fructose to 2,5-dimethyltetrahydrofuran.
Grochowski MR, Yang W, Sen A. Grochowski MR, et al. Chemistry. 2012 Sep 24;18(39):12363-71. doi: 10.1002/chem.201201522. Epub 2012 Aug 22. Chemistry. 2012. PMID: 22915231
Carbohydrates, such as fructose, can be fully dehydroxylated to 2,5-dimethyltetrahydrofuran (DMTHF), a valuable chemical and potential gasoline substitute, by the use of a dual catalytic system consisting of HI and RhX(3) (X=Cl, I). ...
Carbohydrates, such as fructose, can be fully dehydroxylated to 2,5-dimethyltetrahydrofuran (DMTHF), a valuable chemica …
Reaction kinetics of hydrogen abstraction reactions by hydroperoxyl radical from 2-methyltetrahydrofuran and 2,5-dimethyltetrahydrofuran.
Chakravarty HK, Fernandes RX. Chakravarty HK, et al. J Phys Chem A. 2013 Jun 20;117(24):5028-41. doi: 10.1021/jp402801c. Epub 2013 Jun 11. J Phys Chem A. 2013. PMID: 23713783
In this article, we report the rate coefficients for reaction of hydroperoxyl radical (HO2) with 2-methyltetrahydrofuran (MTHF) and 2,5-dimethyltetrahydrofuran (DMTHF) computed employing CBS-QB3 and CCSD(T)/cc-pVTZ//B3LYP/cc-pVTZ level of theory in the temper …
In this article, we report the rate coefficients for reaction of hydroperoxyl radical (HO2) with 2-methyltetrahydrofuran (MTHF) and 2
One-step catalytic transformation of carbohydrates and cellulosic biomass to 2,5-dimethyltetrahydrofuran for liquid fuels.
Yang W, Sen A. Yang W, et al. ChemSusChem. 2010 May 25;3(5):597-603. doi: 10.1002/cssc.200900285. ChemSusChem. 2010. PMID: 20437452
Herein, we report that hexose from a wide range of biomass-derived carbohydrates, cellulose, and even raw lignocellulose (e.g., corn stover) can be converted into 2,5-dimethyltetrahydrofuran (DMTHF) in one step, in good yields and under mild conditions in wat …
Herein, we report that hexose from a wide range of biomass-derived carbohydrates, cellulose, and even raw lignocellulose (e.g., corn stover) …
Catalytic Hydroconversion of 5-HMF to Value-Added Chemicals: Insights into the Role of Catalyst Properties and Feedstock Purity.
Turkin AA, Makshina EV, Sels BF. Turkin AA, et al. ChemSusChem. 2022 Jul 7;15(13):e202200412. doi: 10.1002/cssc.202200412. Epub 2022 Apr 29. ChemSusChem. 2022. PMID: 35348300 Review.
This Review summarizes the most recent advances in heterogeneous catalytic hydroconversion of HMF into valuable chemicals with strong focus on 2,5-bishydroxymethyl furan (BHMF), 2,5-bishydroxymethyltetrahydrofuran (BHMTHF), and 2,5-dimethyltetrahydrofuran (DM …
This Review summarizes the most recent advances in heterogeneous catalytic hydroconversion of HMF into valuable chemicals with strong focus …
22 results