Fluoro-nitrogen Cations.
Vij A, Wilson WW, Haiges R, Edwards KC, Dixon DA, Christe KO.
Vij A, et al.
Angew Chem Int Ed Engl. 2022 Feb 14;61(8):e202116565. doi: 10.1002/anie.202116565. Epub 2022 Jan 10.
Angew Chem Int Ed Engl. 2022.
PMID: 34904338
The influences of the hybridization of the central nitrogen atom and of the number of fluorine substituents on the N-F bond lengths are evaluated for the series N(2) F(+) , N(2) F(3) (+) , NF(2) O(+) , NH(3) F(+) , NH(2) F(2) (+) , and NF(4) (+) . It is shown that the N-F …
The influences of the hybridization of the central nitrogen atom and of the number of fluorine substituents on the N-F bond lengths a …