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Page 1
Biocompatible surface functionalization architecture for a diamond quantum sensor.
Xie M, Yu X, Rodgers LVH, Xu D, Chi-Durán I, Toros A, Quack N, de Leon NP, Maurer PC. Xie M, et al. Proc Natl Acad Sci U S A. 2022 Feb 22;119(8):e2114186119. doi: 10.1073/pnas.2114186119. Proc Natl Acad Sci U S A. 2022. PMID: 35193961 Free PMC article.
Here, we demonstrate an approach that combines quantum engineering with single-molecule biophysics to immobilize individual proteins and DNA molecules on the surface of a bulk diamond crystal that hosts coherent nitrogen vacancy qubit sensors. Our thin (sub-5 nm) functiona …
Here, we demonstrate an approach that combines quantum engineering with single-molecule biophysics to immobilize individual proteins and DNA …
Topology of the electron density of d0 transition metal compounds at subatomic resolution.
Batke K, Eickerling G. Batke K, et al. J Phys Chem A. 2013 Nov 14;117(45):11566-79. doi: 10.1021/jp408576y. Epub 2013 Oct 31. J Phys Chem A. 2013. PMID: 24111934
This commonly used ansatz splits the total electron density of each pseudoatom in the crystal into (i) a spherical core, (ii) a spherical valence, and (iii) a nonspherical valence contribution. ...By a detailed molecular orbital analysis, it is demonstrated that due to the …
This commonly used ansatz splits the total electron density of each pseudoatom in the crystal into (i) a spherical core, (ii) a spher …
Preparation and luminescence properties of Ba2P2O7:Dy3+, Ce3+ phosphors.
Zhao T, Yan M, Pu Y, Zhu D. Zhao T, et al. Spectrochim Acta A Mol Biomol Spectrosc. 2023 Oct 15;299:122874. doi: 10.1016/j.saa.2023.122874. Epub 2023 May 15. Spectrochim Acta A Mol Biomol Spectrosc. 2023. PMID: 37210857
The phase structure, excitation and emission spectra, thermal stability, the chromatic performance of phosphors, and energy transfer from Ce(3+) to Dy(3+) are studied and discussed. The results indicate the samples keep a stable crystal structure as a high-temperature sigm …
The phase structure, excitation and emission spectra, thermal stability, the chromatic performance of phosphors, and energy transfer from Ce …
Effect of Eu3+ doping on structural and optical properties of zirconium titanate.
Akshay S, Vidya YS, Manjunatha HC, Munirathnam, Gurushantha K, Sridhar KN, Prashantha SC. Akshay S, et al. Spectrochim Acta A Mol Biomol Spectrosc. 2023 Nov 15;301:123005. doi: 10.1016/j.saa.2023.123005. Epub 2023 Jun 12. Spectrochim Acta A Mol Biomol Spectrosc. 2023. PMID: 37327499
All the synthesized samples crystallize in a pure orthorhombic crystal structure with the space group of Pbcn. The surface and bulk morphology were analyzed. ...
All the synthesized samples crystallize in a pure orthorhombic crystal structure with the space group of Pbcn. The surface and bulk m …
Double perovskite structure: a vibrational and luminescence investigation providing a perspective on crystal field strength.
Li W, Ning L, Tanner PA. Li W, et al. J Phys Chem A. 2012 Jul 12;116(27):7337-44. doi: 10.1021/jp303626v. Epub 2012 Jul 3. J Phys Chem A. 2012. PMID: 22703165
The luminescence spectra are consistent with monoclinic symmetry of these systems. The crystal field parameters from the fitting of the energy level data set of Ba(2)YNbO(6):Eu(3+) enable the crystal field strength to be calculated, and the order of magnitude is Cl( …
The luminescence spectra are consistent with monoclinic symmetry of these systems. The crystal field parameters from the fitting of t …
Spectroscopy and calculations for 4f(N) 4f(N-1)5d transitions of lanthanide ions in K3YF6.
Ma CG, Brik MG, Ryba-Romanowski W, Swart HC, Gusowski MA. Ma CG, et al. J Phys Chem A. 2012 Sep 13;116(36):9158-80. doi: 10.1021/jp306409p. Epub 2012 Aug 28. J Phys Chem A. 2012. PMID: 22881828
For this theoretical analysis, the extended phenomenological crystal-field model for the 4f(N-1)5d configuration (i.e., the extended f-shell programs, developed by Prof. ...In addition to the studies of the 4f-5d transitions, various possible competitive exci …
For this theoretical analysis, the extended phenomenological crystal-field model for the 4f(N-1)5d configuration (i.e., the ex …
Luminescence and energy transfer in Lu3Al5O12 scintillators co-doped with Ce3+ and Tb3+.
Ogiegło JM, Zych A, Ivanovskikh KV, Jüstel T, Ronda CR, Meijerink A. Ogiegło JM, et al. J Phys Chem A. 2012 Aug 23;116(33):8464-74. doi: 10.1021/jp301337f. Epub 2012 Aug 14. J Phys Chem A. 2012. PMID: 22835039
Tb(3+) 4f-5d transitions to the high spin (HS) and low spin (LS) states are observed (including a zero-phonon line and vibrational structure for the high spin state). The HS-LS splitting of 5400 cm(-1) is smaller than usually observed and is explained by a reduction of the …
Tb(3+) 4f-5d transitions to the high spin (HS) and low spin (LS) states are observed (including a zero-phonon line and vibrational st …
Rational design principles for giant spin Hall effect in 5d-transition metal oxides.
Jadaun P, Register LF, Banerjee SK. Jadaun P, et al. Proc Natl Acad Sci U S A. 2020 Jun 2;117(22):11878-11886. doi: 10.1073/pnas.1922556117. Epub 2020 May 18. Proc Natl Acad Sci U S A. 2020. PMID: 32424094 Free PMC article.
Arising from our key insight regarding the inherently geometric nature of SHE, we demonstrate that two of these design principles are weak crystal fields and the presence of structural distortions. Moreover, we discover that antiperovskites are a highly promising class of …
Arising from our key insight regarding the inherently geometric nature of SHE, we demonstrate that two of these design principles are weak …
Luminescence and luminescence quenching in Gd3(Ga,Al)5O12 scintillators doped with Ce3+.
Ogiegło JM, Katelnikovas A, Zych A, Jüstel T, Meijerink A, Ronda CR. Ogiegło JM, et al. J Phys Chem A. 2013 Mar 28;117(12):2479-84. doi: 10.1021/jp309572p. Epub 2013 Mar 18. J Phys Chem A. 2013. PMID: 23469825
The optical properties of gadolinium gallium aluminum garnet, Gd3(Ga,Al)5O12, doped with Ce(3+) are investigated as a function of the Ga/Al ratio, aimed at an improved understanding of the energy flow and luminescence quenching in these materials. A decrease of both the crysta …
The optical properties of gadolinium gallium aluminum garnet, Gd3(Ga,Al)5O12, doped with Ce(3+) are investigated as a function of the Ga/Al …
Site regulation and luminescence properties of Eu3+, Eu2+ in (La, Mg):SrAl12O19 matrix.
Zou Z, Guo T, Gong G, Lin F, Sun Y, Huang J, Liao J, Wen H. Zou Z, et al. Spectrochim Acta A Mol Biomol Spectrosc. 2023 Dec 5;302:123053. doi: 10.1016/j.saa.2023.123053. Epub 2023 Jun 19. Spectrochim Acta A Mol Biomol Spectrosc. 2023. PMID: 37393668
The temperature-depended fluorescence quenching behavior confirms the essence of strong electric-phonon coupling originated from distorted and polarized crystal field around Eu(2+)/Sr(2+) site. Basing on site regulation of SrAl(12)O(19) matrix, our study provides a referen …
The temperature-depended fluorescence quenching behavior confirms the essence of strong electric-phonon coupling originated from distorted a …
42 results