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Page 1
Modulating Thermal Properties of Polymers through Crystal Engineering.
Germann LS, Carlino E, Taurino A, Magdysyuk OV, Voinovich D, Dinnebier RE, Bučar DK, Hasa D. Germann LS, et al. Angew Chem Int Ed Engl. 2023 May 2;62(19):e202212688. doi: 10.1002/anie.202212688. Epub 2023 Feb 1. Angew Chem Int Ed Engl. 2023. PMID: 36617841 Free PMC article.
Crystal engineering has exclusively focused on the development of advanced materials based on small organic molecules. ...Isomorphous replacement of one of the cocrystal components enables the formation of solid solutions with melting points that can be readily fine-tuned …
Crystal engineering has exclusively focused on the development of advanced materials based on small organic molecules. ...Isomorphous …
Coherent Diffraction Imaging in Transmission Electron Microscopy for Atomic Resolution Quantitative Studies of the Matter.
Carlino E, Scattarella F, Caro L, Giannini C, Siliqi D, Colombo A, Galli DE. Carlino E, et al. Materials (Basel). 2018 Nov 19;11(11):2323. doi: 10.3390/ma11112323. Materials (Basel). 2018. PMID: 30463217 Free PMC article. Review.
Here, it is shown how augmented coherent diffraction imaging makes it possible to achieve quantitative atomic resolution maps of the specimen atomic species, even in the presence of low atomic number atoms within a crystal matrix containing heavy atoms. This aim is achieve …
Here, it is shown how augmented coherent diffraction imaging makes it possible to achieve quantitative atomic resolution maps of the specime …
Cooperative coupling and role of heme a in the proton pump of heme-copper oxidases.
Papa S, Capitanio N, Villani G, Capitanio G, Bizzoca A, Palese LL, Carlino V, De Nitto E. Papa S, et al. Biochimie. 1998 Oct;80(10):821-36. doi: 10.1016/s0300-9084(00)88877-x. Biochimie. 1998. PMID: 9893941 Review.
The vectorial Bohr mechanism is based on short- and long-range protonmotive cooperative effects linked to redox transitions of the metal centers. The crystal structure of oxidized and reduced bovine-heart cytochrome c oxidase reveals, upon reduction, the occurrence of long …
The vectorial Bohr mechanism is based on short- and long-range protonmotive cooperative effects linked to redox transitions of the metal cen …
Selective Formation, Reactivity, Redox and Magnetic Properties of MnIII and FeIII Dinuclear Complexes with Shortened Salen-Type Schiff Base Ligands.
Rigamonti L, Zardi P, Carlino S, Demartin F, Castellano C, Pigani L, Ponti A, Ferretti AM, Pasini A. Rigamonti L, et al. Int J Mol Sci. 2020 Oct 23;21(21):7882. doi: 10.3390/ijms21217882. Int J Mol Sci. 2020. PMID: 33114262 Free PMC article.
The selective formation of the dinuclear complexes [M(2)(mu-salmp)(2)], M = Mn (1a), Fe (2a), [M(2)(mu-salmen)(2)(mu-OR)(2))], R = Et, Me, H and M = Mn (3a-c) or Fe (4a-c), and (M(2)(mu-sal[p-X]ben)(2)(mu-OMe)(2)), X = tBu, Me, H, F, Cl, CF(3), NO(2) and M = Mn (5a-g) or Fe (6a-g …
The selective formation of the dinuclear complexes [M(2)(mu-salmp)(2)], M = Mn (1a), Fe (2a), [M(2)(mu-salmen)(2)(mu-OR)(2))], R = Et, Me, H …
Molecular Dynamics Simulations and Classical Multidimensional Scaling Unveil New Metastable States in the Conformational Landscape of CDK2.
Pisani P, Caporuscio F, Carlino L, Rastelli G. Pisani P, et al. PLoS One. 2016 Apr 21;11(4):e0154066. doi: 10.1371/journal.pone.0154066. eCollection 2016. PLoS One. 2016. PMID: 27100206 Free PMC article.
A low dimensional conformational landscape of CDK2 was modeled using classical multidimensional scaling on a set of 255 crystal structures. Microsecond-scale plain and accelerated MD simulations were used to populate this landscape by using an out-of-sample extension of mu …
A low dimensional conformational landscape of CDK2 was modeled using classical multidimensional scaling on a set of 255 crystal struc …
Nonhydrolytic synthesis of high-quality anisotropically shaped brookite TiO2 nanocrystals.
Buonsanti R, Grillo V, Carlino E, Giannini C, Kipp T, Cingolani R, Cozzoli PD. Buonsanti R, et al. J Am Chem Soc. 2008 Aug 20;130(33):11223-33. doi: 10.1021/ja803559b. Epub 2008 Jul 23. J Am Chem Soc. 2008. PMID: 18646847
Such degree of control is rationalized within the frame of a self-regulated phase-changing seed-catalyzed mechanism, in which homogeneous nucleation, on one side, and heterogeneous nucleation/growth processes, on the other side, are properly balanced while switching from the anat …
Such degree of control is rationalized within the frame of a self-regulated phase-changing seed-catalyzed mechanism, in which homogeneous nu …
Electron diffractive imaging of oxygen atoms in nanocrystals at sub-ångström resolution.
De Caro L, Carlino E, Caputo G, Cozzoli PD, Giannini C. De Caro L, et al. Nat Nanotechnol. 2010 May;5(5):360-5. doi: 10.1038/nnano.2010.55. Epub 2010 Apr 4. Nat Nanotechnol. 2010. PMID: 20364132
Our approach, which does not require spherical and chromatic aberration correction, can reveal the location of light atoms (oxygen) in the crystal lattice. We find that the unit cell in nanoscale TiO(2) is subtly different to that in the corresponding bulk....
Our approach, which does not require spherical and chromatic aberration correction, can reveal the location of light atoms (oxygen) in the …
Hyperbranched anatase TiO2 nanocrystals: nonaqueous synthesis, growth mechanism, and exploitation in dye-sensitized solar cells.
Buonsanti R, Carlino E, Giannini C, Altamura D, De Marco L, Giannuzzi R, Manca M, Gigli G, Cozzoli PD. Buonsanti R, et al. J Am Chem Soc. 2011 Nov 30;133(47):19216-39. doi: 10.1021/ja208418z. Epub 2011 Nov 8. J Am Chem Soc. 2011. PMID: 22004553
A colloidal crystal-splitting growth regime has been accessed, in which TiO(2) nanocrystals, selectively trapped in the metastable anatase phase, can evolve to anisotropic shapes with tunable hyperbranched topologies over a broad size interval. ...Finally, as a proof of fu …
A colloidal crystal-splitting growth regime has been accessed, in which TiO(2) nanocrystals, selectively trapped in the metastable an …
Keyhole electron diffractive imaging (KEDI).
De Caro L, Carlino E, Vittoria FA, Siliqi D, Giannini C. De Caro L, et al. Acta Crystallogr A. 2012 Nov;68(Pt 6):687-702. doi: 10.1107/S0108767312031832. Epub 2012 Sep 7. Acta Crystallogr A. 2012. PMID: 23075611
Hence, the KEDI method has been demonstrated by simulations and experiments performed on an Si crystal cross section in the [112] zone-axis orientation, achieving a resolution of 71 pm....
Hence, the KEDI method has been demonstrated by simulations and experiments performed on an Si crystal cross section in the [112] zon …
12 results