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Page 1
Multiple grafting to enzymatically synthesized polyesters.
Bilal MH, Alaneed R, Steiner J, Mäder K, Pietzsch M, Kressler J. Bilal MH, et al. Methods Enzymol. 2019;627:57-97. doi: 10.1016/bs.mie.2019.04.031. Epub 2019 May 29. Methods Enzymol. 2019. PMID: 31630748
Poly(glycerol adipate) was synthesized by enzymatic transesterification between glycerol and divinyl adipate or dimethyl adipate. Methods are also reported to graft poly(glycerol adipate) with different amounts of hydrophobic side chains (lauric, stearic, behenic, a …
Poly(glycerol adipate) was synthesized by enzymatic transesterification between glycerol and divinyl adipate or dimethyl adipa …
Straightforward Enzymatic Methacrylation of Poly(Glycerol Adipate) for Potential Applications as UV Curing Systems.
Hevilla V, Sonseca Á, Fernández-García M. Hevilla V, et al. Polymers (Basel). 2023 Jul 14;15(14):3050. doi: 10.3390/polym15143050. Polymers (Basel). 2023. PMID: 37514438 Free PMC article.
Enzymatic one-pot synthesis procedures in a one-step and two-step monomers addition were developed to obtain poly(glycerol adipate) macromers with methacrylate end-functional groups under the presence of 1 and 3 wt% of Candida antarctica lipase B (CALB). Glycerol, divinyl …
Enzymatic one-pot synthesis procedures in a one-step and two-step monomers addition were developed to obtain poly(glycerol adipate) macromer …
Enzymatic acylation improves the stability and bioactivity of lutein: Protective effects of acylated lutein derivatives on L-O2 cells upon H2O2-induced oxidative stress.
Tan X, Li H, Huang W, Ma W, Lu Y, Yan R. Tan X, et al. Food Chem. 2023 Jun 1;410:135393. doi: 10.1016/j.foodchem.2023.135393. Epub 2023 Jan 3. Food Chem. 2023. PMID: 36621337
The instability of lutein has limited its wide application especially in the food industry. In this study, enzymatic acylation of lutein with divinyl adipate was investigated. Three new acylated lutein derivatives, lutein-3-O-adipate (compound 1), lutein-3'-O-adipat …
The instability of lutein has limited its wide application especially in the food industry. In this study, enzymatic acylation of lutein wit …
Emulsion Templated Porous Poly(thiol-enes): Influence of Photopolymerisation, Emulsion Composition, and Phase Behaviour on the Porous Structure and Morphology.
Hobiger V, Paljevac M, Krajnc P. Hobiger V, et al. Polymers (Basel). 2022 Mar 25;14(7):1338. doi: 10.3390/polym14071338. Polymers (Basel). 2022. PMID: 35406212 Free PMC article.
1,6-hexanediol diacrylate (HDDA) or divinyl adipate (DVA) and pentaerythritol tetrakis(3-mercaptopropionate) (TT) were polymerised via a thiol-ene radical initiated photopolymerisation using emulsions with a high volume fraction of internal droplet phase and monomer …
1,6-hexanediol diacrylate (HDDA) or divinyl adipate (DVA) and pentaerythritol tetrakis(3-mercaptopropionate) (TT) were polymer …
Enzymatic synthesis of hydrophilic phytosterol polyol esters and assessment of their bioaccessibility and uptake using an in vitro digestion/Caco-2 cell model.
Hu YY, Ma CG, Zhou TL, Bai G, Guo SJ, Chen XW. Hu YY, et al. Food Chem. 2022 Feb 15;370:131324. doi: 10.1016/j.foodchem.2021.131324. Epub 2021 Oct 6. Food Chem. 2022. PMID: 34788959
A novel enzyme-catalyzed method was developed for the synthesis of phytosterol polyol esters from beta-sitosterol and polyols (sorbitol, mannitol and xylitol) by two-step transesterification using divinyl adipate (DVA) as a link. A high conversion (exceeding 94%) of …
A novel enzyme-catalyzed method was developed for the synthesis of phytosterol polyol esters from beta-sitosterol and polyols (sorbitol, man …
Properties of acyl modified poly(glycerol-adipate) comb-like polymers and their self-assembly into nanoparticles.
Taresco V, Suksiriworapong J, Creasey R, Burley JC, Mantovani G, Alexander C, Treacher K, Booth J, Garnett MC. Taresco V, et al. J Polym Sci A Polym Chem. 2016 Oct 15;54(20):3267-3278. doi: 10.1002/pola.28215. Epub 2016 Jul 8. J Polym Sci A Polym Chem. 2016. PMID: 28781423 Free PMC article.
Poly(glycerol-adipate) (PGA) is a biocompatible, biodegradable amphiphilic polyester routinely produced from divinyl adipate and unprotected glycerol by an enzymatic route, bearing a hydroxyl group that can be further functionalized. ...
Poly(glycerol-adipate) (PGA) is a biocompatible, biodegradable amphiphilic polyester routinely produced from divinyl adipate a …
Microcellular open porous monoliths for cell growth by thiol-ene polymerization of low-toxicity monomers in high internal phase emulsions.
Sušec M, Liska R, Russmüller G, Kotek J, Krajnc P. Sušec M, et al. Macromol Biosci. 2015 Feb;15(2):253-61. doi: 10.1002/mabi.201400219. Epub 2014 Oct 8. Macromol Biosci. 2015. PMID: 25294695
Open porous microcellular polymers with high degrees of porosity are prepared from divinyl adipate and pentaerythritol tetrakis(3-mercaptopropionate) by thiol-ene polymerization within high internal phase emulsions. ...
Open porous microcellular polymers with high degrees of porosity are prepared from divinyl adipate and pentaerythritol tetraki …
A gel polymer electrolyte based on PVDF-HFP modified double polymer matrices via ultraviolet polymerization for lithium-sulfur batteries.
Hao X, Wenren H, Wang X, Xia X, Tu J. Hao X, et al. J Colloid Interface Sci. 2020 Jan 15;558:145-154. doi: 10.1016/j.jcis.2019.09.116. Epub 2019 Sep 30. J Colloid Interface Sci. 2020. PMID: 31586734
Herein, we synthesize GPEs polymerized under ultraviolet, in which the poly(vinylidene fluoride-hexafluoro propylene) (PVDF-HFP) is one of the polymer matrices to provide high ionic conductivity and toughness, pentaerythritol tetrakis-divinyl adipate (PETT-DA) is an …
Herein, we synthesize GPEs polymerized under ultraviolet, in which the poly(vinylidene fluoride-hexafluoro propylene) (PVDF-HFP) is one of t …
Preparation of Polyester PolyMIPEs by Polycondensation of Low-Molecular Weight Polyol and Divinyl Ester Using Microwave Activation.
Barbara I, Dourges MA, Deleuze H. Barbara I, et al. Macromol Rapid Commun. 2018 Dec;39(24):e1800632. doi: 10.1002/marc.201800632. Epub 2018 Oct 22. Macromol Rapid Commun. 2018. PMID: 30350389
Several stable non-aqueous apolar-in-polar medium internal phase emulsions (MIPEs) containing divinyl adipate and pentaerythritol in the continuous phase are formulated by varying the nature of the hydrocarbon. ...
Several stable non-aqueous apolar-in-polar medium internal phase emulsions (MIPEs) containing divinyl adipate and pentaerythri …
Enzyme-catalyzed polycondensation of polyester macrodiols with divinyl adipate: a green method for the preparation of thermoplastic block copolyesters.
Dai S, Xue L, Zinn M, Li Z. Dai S, et al. Biomacromolecules. 2009 Dec 14;10(12):3176-81. doi: 10.1021/bm9011634. Biomacromolecules. 2009. PMID: 19919068
Novozym 435-catalyzed reaction of PHB-diol (M(n) of 3100 g/mol, GPC), PHO-diol (M(n) of 3200 g/mol, GPC), and divinyl adipate gave block poly(HB-co-HO) (M(n) of 9800 g/mol, GPC) with randomly arranged blocks in 55% yield. In two-step polycondensations, Novozym 435-c …
Novozym 435-catalyzed reaction of PHB-diol (M(n) of 3100 g/mol, GPC), PHO-diol (M(n) of 3200 g/mol, GPC), and divinyl adipate …
17 results