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Time-resolved keto-enol tautomerization of the medicinal pigment curcumin.
Leung MHM, Addicoat MA, Lincoln SF, Metha GF, Kee TW. Leung MHM, et al. Phys Chem Chem Phys. 2024 May 13. doi: 10.1039/d4cp01006j. Online ahead of print. Phys Chem Chem Phys. 2024. PMID: 38739372
The rate constant of tautomerization of curcumin shows a temperature dependence and analysis using the Arrhenius equation revealed activation energies (E(a)) of tautomerization of (80.1 5.9), (64.1 1.0) and (68.3 5.5) kJ mol(-1) in methanol, D(2)O/acetone and D …
The rate constant of tautomerization of curcumin shows a temperature dependence and analysis using the Arrhenius equation revealed activatio …
Aficamten for Symptomatic Obstructive Hypertrophic Cardiomyopathy.
Maron MS, Masri A, Nassif ME, Barriales-Villa R, Arad M, Cardim N, Choudhury L, Claggett B, Coats CJ, Düngen HD, Garcia-Pavia P, Hagège AA, Januzzi JL, Lee MMY, Lewis GD, Ma CS, Michels M, Olivotto I, Oreziak A, Owens AT, Spertus JA, Solomon SD, Tfelt-Hansen J, van Sinttruije M, Veselka J, Watkins H, Jacoby DL, Heitner SB, Kupfer S, Malik FI, Meng L, Wohltman A, Abraham TP; SEQUOIA-HCM Investigators. Maron MS, et al. N Engl J Med. 2024 May 13. doi: 10.1056/NEJMoa2401424. Online ahead of print. N Engl J Med. 2024. PMID: 38739079
Mechanism of CO2 in promoting the hydrogenation of levulinic acid to γ-valerolactone catalyzed by RuCl3 in aqueous solution.
Min HY, Xiong JS, Liu TH, Fu S, Hu CW, Yang HQ. Min HY, et al. Phys Chem Chem Phys. 2024 May 13. doi: 10.1039/d4cp00753k. Online ahead of print. Phys Chem Chem Phys. 2024. PMID: 38739028
Herein, we report the competitive mechanisms for the hydrogenation of LA to GVL, 4-oxopentanal (OT), and 2-methyltetrahydro-2,5-furandiol (MFD) with HCOOH or H(2) as the H source catalyzed by RuCl(3) in aqueous solution at the M06/def2-TZVP, 6-311++G(d,p) theoretical level …
Herein, we report the competitive mechanisms for the hydrogenation of LA to GVL, 4-oxopentanal (OT), and 2-methyltetrahydro-2,5-furandiol (M …
Binucleating Jager-type {(N(2)O(2))(2)}(4-) ligands: magnetic and electronic interactions of Fe(II), Ni(II) and Cu(II) across an in-plane TTF-bridge.
Schreck C, Schönfeld S, Liebing P, Hörner G, Weber B. Schreck C, et al. Dalton Trans. 2024 May 13. doi: 10.1039/d4dt00479e. Online ahead of print. Dalton Trans. 2024. PMID: 38738956
Herein, we present the incorporation of a twice-reversibly oxidizable tetrathiafulvalene (TTF) unit into a binucleating ligand, bridging two metal centers in a fully conjugated plane. A two-step synthesis scheme gave the D(2h) symmetric Schiff base-like ligand H(4)L in mod …
Herein, we present the incorporation of a twice-reversibly oxidizable tetrathiafulvalene (TTF) unit into a binucleating ligand, bridging two …
Self-assembly of Ni(II) with a chiral ligand pair vs. mixture of the chiral ligand pair: structural features and recognition ability of Ni2L4 cages.
Han J, Back HJ, Hossain MM, Jung OS, Lee YA. Han J, et al. Dalton Trans. 2024 May 13. doi: 10.1039/d4dt00762j. Online ahead of print. Dalton Trans. 2024. PMID: 38738336
The most interesting feature is that the self-assembly of NiCl(2) with the mixture of r,s-L and s,r-L (1 : 1-1 : 4) produces crystals of thermodynamically stable achiral cages, [2Cl.2H(2)O@Ni(2)Cl(2)(s,r-L)(2)(r,s-L)(2)(H(2)O)(2)].7C(4)H(8)O(2), in the molar …
The most interesting feature is that the self-assembly of NiCl(2) with the mixture of r,s-L and s,r-L (1 : 1-1 : 4) produces crystals of the …
In vitro antimicrobial, anticancer evaluation, and in silico studies of mannopyranoside analogs against bacterial and fungal proteins: Acylation leads to improved antimicrobial activity.
Ahad Hossain M, Sultana S, Alanazi MM, Hadni H, Bhat AR, Hasan I, Kawsar SMA. Ahad Hossain M, et al. Saudi Pharm J. 2024 Jun;32(6):102093. doi: 10.1016/j.jsps.2024.102093. Epub 2024 Apr 30. Saudi Pharm J. 2024. PMID: 38737807 Free PMC article.
Thus, we explored the various therapeutic potential of methyl alpha-D-mannopyranoside (MalphaDM) analogs, including their ability to synthesize and assess their antibacterial, antifungal, and anticancer properties; additionally, molecular docking, molecular dynamics simula …
Thus, we explored the various therapeutic potential of methyl alpha-D-mannopyranoside (MalphaDM) analogs, including their ability to …
Distinct autoantibody profiles across checkpoint inhibitor types and toxicities.
Mu-Mosley H, von Itzstein MS, Fattah F, Liu J, Zhu C, Xie Y, Wakeland EK, Park JY, Kahl BS, Diefenbach CS, Gerber DE. Mu-Mosley H, et al. Oncoimmunology. 2024 May 9;13(1):2351255. doi: 10.1080/2162402X.2024.2351255. eCollection 2024. Oncoimmunology. 2024. PMID: 38737792 Free PMC article. Clinical Trial.
Three undescribed dihydrostilbene glycosides from leaves of Camellia oleifera Abel. And their anti-inflammatory activity.
Xu Y, Tang SQ, Suo ZW, Wei KX, Luyten W, Huang H, Li XJ. Xu Y, et al. Heliyon. 2024 Apr 30;10(9):e30507. doi: 10.1016/j.heliyon.2024.e30507. eCollection 2024 May 15. Heliyon. 2024. PMID: 38737284 Free PMC article.
The undescribed secondary metabolites 1-3 were elucidated as 3,5-dimethoxydihydrostilbene 4'-O-alpha-l-arabinofuranosyl-(1 6)-beta-d- glucopyranoside, 3,5-dimethoxydihydrostilbene 4'-O-alpha-l-arabinopyranosyl-(1 6)-beta-d- glucopyranoside and 3,5-dime …
The undescribed secondary metabolites 1-3 were elucidated as 3,5-dimethoxydihydrostilbene 4'-O-alpha-l-arabinofuranosyl-(1 6)-beta- …
Changes in transcriptomic landscape with macronutrients intake switch are independent from O-GlcNAcylation levels in heart throughout postnatal development in rats.
Persello A, Dupas T, Vergnaud A, Blangy-Letheule A, Aillerie V, Erraud A, Guilloux Y, Denis M, Lauzier B. Persello A, et al. Heliyon. 2024 Apr 30;10(9):e30526. doi: 10.1016/j.heliyon.2024.e30526. eCollection 2024 May 15. Heliyon. 2024. PMID: 38737268 Free PMC article.
We wanted to unveil if O-GlcNAcylation is linking metabolic transition to transcriptomic changes and to highlight modifications of O-GlcNAcylation during the postnatal cardiac development. ...CONCLUSION: Macronutrients switch promotes changes in the transcriptome la …
We wanted to unveil if O-GlcNAcylation is linking metabolic transition to transcriptomic changes and to highlight modifications of …
Geochemical Characteristics and Geological Significance of Coalbed Methane in Suzhou Mining Area of the Huaibei Coalfield.
Wei Q, Chen S, Gui H, Zhao M, Zhao K, Xia H, Wu C. Wei Q, et al. ACS Omega. 2024 Apr 22;9(18):20086-20100. doi: 10.1021/acsomega.3c10512. eCollection 2024 May 7. ACS Omega. 2024. PMID: 38737092 Free PMC article.
Results have shown that the selected CBM reservoirs are characterized by various thickness (0.50-9.19 m) and buried depth (619-1226 m), but have relatively better lithology of surrounding rocks. Coal samples have similar maturity (R(o,max) = 0.71-1.05%), but show differenc …
Results have shown that the selected CBM reservoirs are characterized by various thickness (0.50-9.19 m) and buried depth (619-1226 m), but …
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