Structure and reactivity of the N-acetyl-cysteine radical cation and anion: does radical migration occur?
Osburn S, Berden G, Oomens J, O'Hair RA, Ryzhov V.
Osburn S, et al.
J Am Soc Mass Spectrom. 2011 Oct;22(10):1794-803. doi: 10.1007/s13361-011-0198-5. Epub 2011 Jul 16.
J Am Soc Mass Spectrom. 2011.
PMID: 21952893
The radical cation was generated by first nitrosylating the thiol of N-acetyl-cysteine followed by the homolytic cleavage of the S-NO bond in the gas phase. IRMPD spectroscopy coupled with DFT calculations revealed that for the radical cation the radical migrates from its …
The radical cation was generated by first nitrosylating the thiol of N-acetyl-cysteine followed by the homolytic cleavage of the S-NO …