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Page 1
Stereoselective epoxidation of phenyl allyl ether by alkene-utilizing bacteria.
Mahmoudian M, Michael A. Mahmoudian M, et al. Appl Microbiol Biotechnol. 1992 Apr;37(1):28-31. doi: 10.1007/BF00174198. Appl Microbiol Biotechnol. 1992. PMID: 1368499
Eighteen newly isolated ethene- and propene-utilizing bacteria were screened for the ability to produce phenyl glycidyl ether, a common precursor for the synthesis of beta blockers, from phenyl allyl ether. These organisms included Aerococcus, Alcaligenes, Mi …
Eighteen newly isolated ethene- and propene-utilizing bacteria were screened for the ability to produce phenyl glycidyl ether, a common prec …
Improved iterative synthesis of linearly disassembling dendrons.
Ortiz A, Shanahan CS, Sisk DT, Perera SC, Rao P, McGrath DV. Ortiz A, et al. J Org Chem. 2010 Sep 17;75(18):6154-62. doi: 10.1021/jo1009849. J Org Chem. 2010. PMID: 20738148
We have prepared multigram quantities of first- through third-generation linearly disassembling dendrons containing a [3-N,4-O]-benzylaryl ether disassembly pathway, capped by a vanillin-derived phenyl allyl ether trigger, and a p-nitrophenoxy (PNP) reporter …
We have prepared multigram quantities of first- through third-generation linearly disassembling dendrons containing a [3-N,4-O]-benzylaryl e …
LiCB(11)Me(12): a catalyst for pericyclic rearrangements.
Moss S, King BT, de Meijere A, Kozhushkov SI, Eaton PE, Michl J. Moss S, et al. Org Lett. 2001 Jul 26;3(15):2375-7. doi: 10.1021/ol0161864. Org Lett. 2001. PMID: 11463320
[structure: see text] Benzene and 1,2-dichloroethane solutions of the Li(+) salt of the weakly coordinating anion CB(11)Me(12)(-) catalyze the rearrangement of cubane to cuneane, quadricyclane to norbornadiene, basketene to Nenitzescu's hydrocarbon, and diademane to triquinacene. …
[structure: see text] Benzene and 1,2-dichloroethane solutions of the Li(+) salt of the weakly coordinating anion CB(11)Me(12)(-) catalyze t …
Use of silica gels and mesoporous molecular sieves as supports for the solid-phase Claisen rearrangement.
Sucholeiki I, Pavia MR, Kresge CT, McCullen SB, Malek A, Schramm S. Sucholeiki I, et al. Mol Divers. 1997-1998;3(3):161-71. doi: 10.1023/a:1009687028242. Mol Divers. 1997. PMID: 9680647
Several of these silica based materials were derivatized with the hydroxymethyl benzoic acid linker and used as supports for the solid phase Claisen rearrangement of a support bound phenyl allyl ether. Both the silica gel and mesoporous supports were heated a …
Several of these silica based materials were derivatized with the hydroxymethyl benzoic acid linker and used as supports for the solid phase …
A theoretical study of pericyclic rearrangements catalyzed by lithium.
Montero-Campillo MM, Cabaleiro-Lago EM, Rodríguez-Otero J. Montero-Campillo MM, et al. J Phys Chem A. 2008 Jun 12;112(23):5218-23. doi: 10.1021/jp801130s. Epub 2008 May 20. J Phys Chem A. 2008. PMID: 18491853
The role of lithium cation in the isomerization from diademane to triquinacene and in the Claisen reaction from phenyl allyl ether to 6-allyl-2,4-cyclohexadienone was analyzed. The nature of the interaction of the lithium ion with the reacting molecules in th …
The role of lithium cation in the isomerization from diademane to triquinacene and in the Claisen reaction from phenyl allyl …