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Dioxygenases without requirement for cofactors and their chemical model reaction: compulsory order ternary complex mechanism of 1H-3-hydroxy-4-oxoquinaldine 2,4-dioxygenase involving general base catalysis by histidine 251 and single-electron oxidation of the substrate dianion.
Frerichs-Deeken U, Ranguelova K, Kappl R, Hüttermann J, Fetzner S. Frerichs-Deeken U, et al. Among authors: ranguelova k. Biochemistry. 2004 Nov 16;43(45):14485-99. doi: 10.1021/bi048735u. Biochemistry. 2004. PMID: 15533053
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