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Convenient iterative synthesis of an octameric tetracarboxylate-functionalized oligophenylene rod with divergent end groups.
Read MW, Escobedo JO, Willis DM, Beck PA, Strongin RM. Read MW, et al. Org Lett. 2000 Oct 5;2(20):3201-4. doi: 10.1021/ol000204k. Org Lett. 2000. PMID: 11009381
Oligo(p-phenylene) rigid rod 10 is synthesized via a functional group-tolerant molecular doubling approach. ...
Oligo(p-phenylene) rigid rod 10 is synthesized via a functional group-tolerant molecular doubling approach. ...
Stability of the Gyroid Phase in Rod-Coil Systems via Thermodynamic Integration with Molecular Dynamics.
Nowak C, Escobedo FA. Nowak C, et al. J Chem Theory Comput. 2018 Nov 13;14(11):5984-5991. doi: 10.1021/acs.jctc.8b00419. Epub 2018 Oct 2. J Chem Theory Comput. 2018. PMID: 30216720
The stability of the gyroid phase in a coarse-grained model of rod-coil block copolymers is ascertained by using a field-based thermodynamic integration method to calculate free-energy differences between competing phases. The scope of the original methodology is expanded …
The stability of the gyroid phase in a coarse-grained model of rod-coil block copolymers is ascertained by using a field-based thermo …
Electrokinetic removal of radionuclides contained in scintillation liquids absorbed in soil type Phaeozem.
Valdovinos V, Monroy-Guzmán F, Bustos E. Valdovinos V, et al. J Environ Radioact. 2016 Oct;162-163:80-86. doi: 10.1016/j.jenvrad.2016.05.017. Epub 2016 May 24. J Environ Radioact. 2016. PMID: 27232822
In this sense, the support electrolyte was selected based on the highest current generated (1 mA), as in the case of scintillation liquid 50% Ultima Gold XR + 50% Water (1:1), which was used for 6 h in the presence of a mesh and a titanium rod, as anode and cathode, respec …
In this sense, the support electrolyte was selected based on the highest current generated (1 mA), as in the case of scintillation liquid 50 …
Assembly of porous smectic structures formed from interlocking high-symmetry planar nanorings.
Avendaño C, Jackson G, Müller EA, Escobedo FA. Avendaño C, et al. Proc Natl Acad Sci U S A. 2016 Aug 30;113(35):9699-703. doi: 10.1073/pnas.1604717113. Epub 2016 Aug 18. Proc Natl Acad Sci U S A. 2016. PMID: 27540114 Free PMC article.
We show that these smectic phases possess uniquely high free volumes of up to 95%, a value significantly larger than the 50% that is typically achievable with smectic phases formed by more conventional convex rod- or disklike mesogenic particles....
We show that these smectic phases possess uniquely high free volumes of up to 95%, a value significantly larger than the 50% that is typical …