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Biosynthesis of sesquiterpenes by the fungus Fusarium verticillioides.
Dickschat JS, Brock NL, Citron CA, Tudzynski B. Dickschat JS, et al. Chembiochem. 2011 Sep 5;12(13):2088-95. doi: 10.1002/cbic.201100268. Epub 2011 Jul 11. Chembiochem. 2011. PMID: 21748838
The unusual compound (E)-iso-gamma-bisabolene was also found corroborating a previously suggested mechanism for the cyclisation of the bisabolyl to the cuprenyl cation that is based on quantum mechanical calculations (Y. ...
The unusual compound (E)-iso-gamma-bisabolene was also found corroborating a previously suggested mechanism for the cyclisation of the bisab …
Which is more likely in trichodiene biosynthesis: hydride or proton transfer?
Hong YJ, Tantillo DJ. Hong YJ, et al. Org Lett. 2006 Sep 28;8(20):4601-4. doi: 10.1021/ol061884f. Org Lett. 2006. PMID: 16986960
Using quantum chemical methods (B3LYP/6-31+G(d,p) and mPW1PW91/6-31+G(d,p)), we discovered two alternative pathways for transformation of the intermediate bisabolyl cation to the cuprenyl cation, one of which--a proton-transfer pathway--appears to be much more energeticall …
Using quantum chemical methods (B3LYP/6-31+G(d,p) and mPW1PW91/6-31+G(d,p)), we discovered two alternative pathways for transformation of th …
[The effect of D-penicillamine on the immunological indices of rheumatoid arthritis patients].
Sheĭtanov I. Sheĭtanov I. Vutr Boles. 1990;29(4):59-64. Vutr Boles. 1990. PMID: 2281661 Bulgarian.
In 25 patients with rheumatoid arthritis the action of D-penicilamine (Cuprenyl) on the following indices was studied: IgG, IgA, IgM, circulating immune complexes (CIC), rheumatoid factor titer (RF), T- and B-lymphocytes in the peripheral blood. ...
In 25 patients with rheumatoid arthritis the action of D-penicilamine (Cuprenyl) on the following indices was studied: IgG, IgA, IgM, …