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Showing results for dihalogen
Your search for diclogen retrieved no results
Geminal dihalogen isosteric replacement in hydrated AI-2 affords potent quorum sensing modulators.
Guo M, Zheng Y, Terell JL, Ad M, Opoku-Temeng C, Bentley WE, Sintim HO. Guo M, et al. Chem Commun (Camb). 2015 Feb 14;51(13):2617-20. doi: 10.1039/c4cc09361e. Chem Commun (Camb). 2015. PMID: 25573337
This can be recapitulated with geminal dibromides, via halogen bonding. Geminal dihalogens represent interesting isosteric replacements for hydrated carbonyls in ligands and are currently under-utilized in ligand design....
This can be recapitulated with geminal dibromides, via halogen bonding. Geminal dihalogens represent interesting isosteric replacemen …
Pseudotetrahedral Zn(II)-(R or S)-dihalogen-salicylaldiminato complexes with lambda- or delta-chirality induction at-metal.
Rudbari HA, Saadati A, Aryaeifar M, Blacque O, Correia I, Islam MK, Woschko D, Janiak C, Enamullah M. Rudbari HA, et al. Dalton Trans. 2022 Feb 8;51(6):2385-2399. doi: 10.1039/d1dt04220c. Dalton Trans. 2022. PMID: 35043801
Reactions of enantiopure (S or R)-N-1-(phenyl)ethyl-2,4-X(1),X(2)-salicylaldimine (S-H or R-H; X(1), X(2) = dihalogen) with Zn(II)-nitrate give bis[(S or R)-N-1-(phenyl)ethyl-2,4-X(1),X(2)-salicylaldiminato-kappa(2)N,O]-zinc(II), (delta-ZnS or lambda-ZnR) with delta/lambda …
Reactions of enantiopure (S or R)-N-1-(phenyl)ethyl-2,4-X(1),X(2)-salicylaldimine (S-H or R-H; X(1), X(2) = dihalogen) with Zn(II)-ni …
Silver Complexes of Dihalogen Molecules.
Malinowski PJ, Himmel D, Krossing I. Malinowski PJ, et al. Angew Chem Int Ed Engl. 2016 Aug 1;55(32):9259-61. doi: 10.1002/anie.201603741. Epub 2016 Jul 12. Angew Chem Int Ed Engl. 2016. PMID: 27404568
The perfluorohexane-soluble and donor-free silver compound Ag(A) (A=Al(OR(F) )4 ; R(F) =C(CF3 )3 ) prepared using a facile novel route has unprecedented capabilities to form unusual and weakly bound complexes. Here, we report on the three dihalogen-silver complexes Ag(Cl2 …
The perfluorohexane-soluble and donor-free silver compound Ag(A) (A=Al(OR(F) )4 ; R(F) =C(CF3 )3 ) prepared using a facile novel route has u …
Design, Synthesis, and Antitumor Activity Evaluation of 2-Arylmethoxy-4-(2,2'-dihalogen-substituted biphenyl-3-ylmethoxy) Benzylamine Derivatives as Potent PD-1/PD-L1 Inhibitors.
Zhang H, Zhou S, Plewka J, Wu C, Zhu M, Yu Q, Musielak B, Wang X, Awadasseid A, Magiera-Mularz K, Wu Y, Zhang W. Zhang H, et al. J Med Chem. 2023 Aug 10;66(15):10579-10603. doi: 10.1021/acs.jmedchem.3c00731. Epub 2023 Jul 26. J Med Chem. 2023. PMID: 37496104
Novel 2-arylmethoxy-4-(2,2'-dihalogen-substituted biphenyl-3-ylmethoxy) benzylamine derivatives were designed, synthesized, and evaluated in vitro and in vivo against cancers as PD-1/PD-L1 inhibitors. ...
Novel 2-arylmethoxy-4-(2,2'-dihalogen-substituted biphenyl-3-ylmethoxy) benzylamine derivatives were designed, synthesized, and evalu …
Competition between halogen, dihalogen and hydrogen bonds in bromo- and iodomethanol dimers.
Riley KE, Rezáč J, Hobza P. Riley KE, et al. J Mol Model. 2013 Jul;19(7):2879-83. doi: 10.1007/s00894-012-1727-2. Epub 2013 Jan 8. J Mol Model. 2013. PMID: 23296565
O-H...X and O-H...O H-bonds as well as C-X...X dihalogen and C-X...O halogen bonds have been investigated in halomethanol dimers (bromomethanol dimer, iodomethanol dimer, difluorobromomethanolbromomethanol complex and difluoroiodomethanoliodomethanol complex). ...The stron …
O-H...X and O-H...O H-bonds as well as C-X...X dihalogen and C-X...O halogen bonds have been investigated in halomethanol dimers (bro …
Catalytic Enantioselective Dihalogenation in Total Synthesis.
Landry ML, Burns NZ. Landry ML, et al. Acc Chem Res. 2018 May 15;51(5):1260-1271. doi: 10.1021/acs.accounts.8b00064. Epub 2018 Apr 17. Acc Chem Res. 2018. PMID: 29664281 Free PMC article. Review.
In this Account, we describe our laboratory's development of a method for catalytic, enantioselective dihalogenation and the application of this method to the synthesis of both mono- and polyhalogenated natural products. ...In reviewing these syntheses, a framework for the …
In this Account, we describe our laboratory's development of a method for catalytic, enantioselective dihalogenation and the applicat …
Thermal Rearrangement of 5-(2-Hydroxy-6-oxocyclohexyl)-5H-chromeno[2,3-b]pyridines.
Ryzhkova YE, Ryzhkov FV, Elinson MN, Vereshchagin AN, Novikov RA, Fakhrutdinov AN. Ryzhkova YE, et al. Molecules. 2023 Mar 31;28(7):3139. doi: 10.3390/molecules28073139. Molecules. 2023. PMID: 37049908 Free PMC article.
Xanthenes, pyridin-2(1H)-ones, and 1,6-naphthyridines have a wide range of biological activities. In this work, we propose the thermal rearrangement of 7,9-dihalogen-substituted 5-(2-hydroxy-6-oxocyclohexyl)-5H-chromeno[2,3-b]pyridines in DMSO. Previously unknown 5,7-di …
Xanthenes, pyridin-2(1H)-ones, and 1,6-naphthyridines have a wide range of biological activities. In this work, we propose the thermal rearr …
Thermochemistry of dihalogen-substituted benzenes: data evaluation using experimental and quantum chemical methods.
Verevkin SP, Emel'yanenko VN, Varfolomeev MA, Solomonov BN, Zherikova KV, Melkhanova SV. Verevkin SP, et al. J Phys Chem B. 2014 Dec 11;118(49):14479-92. doi: 10.1021/jp5097844. Epub 2014 Nov 26. J Phys Chem B. 2014. PMID: 25383788
Temperature dependence of vapor pressures for 12 dihalogen-substituted benzenes (halogen = F, Cl, Br, I) was studied by the transpiration method, and molar vaporization or sublimation enthalpies were derived. ...Evaluated vaporization enthalpies in combination with gas-pha …
Temperature dependence of vapor pressures for 12 dihalogen-substituted benzenes (halogen = F, Cl, Br, I) was studied by the transpira …
456 results