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Showing results for germylene
Search for germolene instead (1 results)
Coinage Metal Complexes of Germylene and Stannylene.
Ghosh M, Sen N, Khan S. Ghosh M, et al. ACS Omega. 2022 Feb 14;7(8):6449-6454. doi: 10.1021/acsomega.1c06771. eCollection 2022 Mar 1. ACS Omega. 2022. PMID: 35252640 Free PMC article. Review.
Group 11 metal (M = Cu, Ag, Au) complexes of heavier tetrylenes (namely, germylene and stannylene) have been studied for several years now. ...
Group 11 metal (M = Cu, Ag, Au) complexes of heavier tetrylenes (namely, germylene and stannylene) have been studied for several year …
Germylene-beta-sulfoxide Hemilabile Ligand in Coordination Chemistry.
Lentz N, Cuevas-Chavez C, Mallet-Ladeira S, Sotiropoulos JM, Baceiredo A, Kato T, Madec D. Lentz N, et al. Inorg Chem. 2021 Jan 4;60(1):423-430. doi: 10.1021/acs.inorgchem.0c03101. Epub 2020 Dec 21. Inorg Chem. 2021. PMID: 33347753
We describe herein the synthesis of a germylene-beta-sulfoxide ligand, 1, and its abilities in coordination chemistry. ...
We describe herein the synthesis of a germylene-beta-sulfoxide ligand, 1, and its abilities in coordination chemistry. ...
Open-Shell Germylene Stabilized by a Phenalenyl-Based Ligand.
Kodama T, Uchida K, Nakasuji C, Kishi R, Kitagawa Y, Tobisu M. Kodama T, et al. Inorg Chem. 2023 May 22;62(20):7861-7867. doi: 10.1021/acs.inorgchem.3c00583. Epub 2023 May 10. Inorg Chem. 2023. PMID: 37163696
An open-shell germylene 1 stabilized by a phenalenyl-based bidentate ligand was synthesized and characterized. ...
An open-shell germylene 1 stabilized by a phenalenyl-based bidentate ligand was synthesized and characterized. ...
An Isolable Bis(Germylene)-Stabilized Plumbylone.
Chen M, Zhang Z, Qiao Z, Zhao L, Mo Z. Chen M, et al. Angew Chem Int Ed Engl. 2023 Jan 23;62(4):e202215146. doi: 10.1002/anie.202215146. Epub 2022 Dec 14. Angew Chem Int Ed Engl. 2023. PMID: 36421062
A preliminary reactivity study demonstrates that complex 3 can deliver Pb(0) atoms to an organic azide producing a tetrameric imido complex [(PbNDipp)(4) ] (Dipp=2,6-(i) Pr-C(6) H(3) , 4) and perform a metathesis reaction with GeCl(2) dioxane to produce a bis(germylene)-st …
A preliminary reactivity study demonstrates that complex 3 can deliver Pb(0) atoms to an organic azide producing a tetrameric imido complex …
Structure and reactivity of germylene-bridged digold complexes.
Wang L, Zhen G, Li Y, Kira M, Yan L, Chang XY, Huang L, Li Z. Wang L, et al. Nat Commun. 2022 Apr 4;13(1):1785. doi: 10.1038/s41467-022-29476-1. Nat Commun. 2022. PMID: 35379820 Free PMC article.
DFT calculations of 3a revealed the existence of high-lying sigma(Ge-Au) type HOMO and low-lying LUMO with germylene p(pi) nature. A pendular motion of AuPR(3) group between Ge(IV) and Ge(II) of 3 occurs in the NMR time scale, suggesting that the Ge(II) center has an enhan …
DFT calculations of 3a revealed the existence of high-lying sigma(Ge-Au) type HOMO and low-lying LUMO with germylene p(pi) nature. A …
sigma,pi-Conjugated Bis(germylene) Adducts with NHC and CAACs.
Thömmes AL, Morgenstern B, Zimmer M, Andrada DM, Scheschkewitz D. Thömmes AL, et al. Chemistry. 2023 Jul 11;29(39):e202301273. doi: 10.1002/chem.202301273. Epub 2023 May 19. Chemistry. 2023. PMID: 37114923
We now report both NHC- and CAAC-coordination to a bridged bis(germylene) motif. The NHC-coordinated bis(germylene) exhibits pyramidal germanium centers with lone pairs of electrons, while with CAAC an unprecedented stable bis(germene) with two Ge=C bonds is isolate …
We now report both NHC- and CAAC-coordination to a bridged bis(germylene) motif. The NHC-coordinated bis(germylene) exhibits p …
A Silylene-Germylene Molecule Containing a Si(I) -Ge(I) Single Bond.
Qin Y, Zheng G, Guo Y, Gao F, Ma J, Sun W, Xie G, Chen S, Wang Y, Sun H, Li A, Wang W. Qin Y, et al. Chemistry. 2020 May 15;26(28):6122-6125. doi: 10.1002/chem.202000836. Epub 2020 May 8. Chemistry. 2020. PMID: 32074403
The first isolable silylene-germylene complex 5 was assembled by a salt metathesis reaction between the germylene anion 3 and the N-heterocyclic chlorosilylene 4, and structurally characterized. ...The latter increases the molecular stability of 3 and 5, and makes t …
The first isolable silylene-germylene complex 5 was assembled by a salt metathesis reaction between the germylene anion 3 and …
Amidinato Germylene-Zinc Complexes: Synthesis, Bonding, and Reactivity.
Yadav S, Kumar R, Vipin Raj K, Yadav P, Vanka K, Sen SS. Yadav S, et al. Chem Asian J. 2020 Oct 1;15(19):3116-3121. doi: 10.1002/asia.202000807. Epub 2020 Sep 4. Chem Asian J. 2020. PMID: 32780439
Despite the explosive growth of germylene compounds as ligands in transition metal complexes, there is a modicum of precedence for the germylene zinc complexes. In this work, the synthesis and characterization of new germylene zinc complexes [PhC(NtBu)(2) Ge{ …
Despite the explosive growth of germylene compounds as ligands in transition metal complexes, there is a modicum of precedence for th …
Insertion Reaction of Me(3)SiN(3) with Bis(germylene).
Ding Y, Sarkar SK, Nazish M, Ruth PN, Herbst-Irmer R, Muhammed S, Parameswaran P, Stalke D, Roesky HW. Ding Y, et al. Inorg Chem. 2022 Dec 5;61(48):19067-19074. doi: 10.1021/acs.inorgchem.2c02252. Epub 2022 Nov 19. Inorg Chem. 2022. PMID: 36401647
The reaction of Me(3)SiN(3) with bis-germylene in a 1:1 molar ratio results in compound 1 at -78 C; however, treatment of bis-germylene with a 2.1 equiv of Me(3)SiN(3) at room temperature results in compound 2. ...These are rare examples of isolated products that sh …
The reaction of Me(3)SiN(3) with bis-germylene in a 1:1 molar ratio results in compound 1 at -78 C; however, treatment of bis-germ …
Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes.
Feng Z, Wang L, Mohammed SNBS, Rao B, Kinjo R. Feng Z, et al. Chem Asian J. 2023 Oct 4;18(19):e202300634. doi: 10.1002/asia.202300634. Epub 2023 Sep 6. Chem Asian J. 2023. PMID: 37641951
The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. ...Chlorine abstraction of 6 gives the cationic germylene gold(I) complex 7....
The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. ...Chlorine abstract …
340 results