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Dominant conformer of tetrahydropyran-2-methanol and its clusters in the gas phase explored by the use of VUV photoionization and vibrational spectroscopy.
Zhan H, Hu Y, Wang P, Chen J. Zhan H, et al. J Chem Phys. 2017 Apr 7;146(13):134303. doi: 10.1063/1.4979298. J Chem Phys. 2017. PMID: 28390350
Tetrahydropyran-2-methanol (THPM) is a typical alcohol containing a six-member cyclic ether, which can be considered as the model molecule of cyclic sugar. ...
Tetrahydropyran-2-methanol (THPM) is a typical alcohol containing a six-member cyclic ether, which can be considered as …
Studies on alpha-sialylation using sialyl donors with an auxiliary 3-thiophenyl group.
Martichonok V, Whitesides GM. Martichonok V, et al. Carbohydr Res. 1997 Aug 7;302(3-4):123-9. doi: 10.1016/s0008-6215(97)00094-3. Carbohydr Res. 1997. PMID: 9291567
Reaction of the methyl ester of 2-chloro-3-S-phenyl-3-thiosialic acid (4) with sodium thiomethoxide in acetonitrile at 0 degrees C affords the methyl ester of 2-S-methyl-3-S-phenyl-2,3-di-thio-alpha-sialic acid (6a) in quantitative yield. Sialylation of tetrahydropyran- …
Reaction of the methyl ester of 2-chloro-3-S-phenyl-3-thiosialic acid (4) with sodium thiomethoxide in acetonitrile at 0 degrees C affords t …
Selective inhibition of metabolic enzymes by enzymatically synthesized D-glucal-6-phosphate.
Chenault HK, Mandes RF. Chenault HK, et al. Bioorg Med Chem. 1994 Jul;2(7):627-9. doi: 10.1016/0968-0896(94)85010-0. Bioorg Med Chem. 1994. PMID: 7858968
Yeast hexokinase (EC 2.7.1.1) catalyzes the phosphorylation of D-glucal and methyl alpha- and beta-D-glucopyranosides at 1-5% of the rates of phosphorylation of D-glucose and 2-deoxy-D-glucose. Maltose, cellobiose, D-galactal and tetrahydropyran-2-methanol ar …
Yeast hexokinase (EC 2.7.1.1) catalyzes the phosphorylation of D-glucal and methyl alpha- and beta-D-glucopyranosides at 1-5% of the rates o …