Atomically Precise Defective Copper Nanocluster Catalysts for Highly Selective C-C Cross-Coupling Reactions.
Nematulloev S, Sagadevan A, Alamer B, Shkurenko A, Huang R, Yin J, Dong C, Yuan P, Yorov KE, Karluk AA, Mir WJ, Hasanov BE, Nejib Hedhili M, Halappa NM, Eddaoudi M, Mohammed OF, Rueping M, Bakr OM.
Nematulloev S, et al.
Angew Chem Int Ed Engl. 2023 Jun 26;62(26):e202303572. doi: 10.1002/anie.202303572. Epub 2023 May 16.
Angew Chem Int Ed Engl. 2023.
PMID: 37130272
Herein, we report the synthesis of novel atomically precise, copper hydride nanoclusters (NCs), [Cu(28) H(10) (C(7) H(7) S)(18) (TPP)(3) ] (Cu(28) ; TPP: triphenylphosphine; C(7) H(7) S: o-thiocresol) with a defined defect in the gram scale via a one-pot reduction method. …
Herein, we report the synthesis of novel atomically precise, copper hydride nanoclusters (NCs), [Cu(28) H(10) (C(7) H(7) S)(18) (TPP)(3) ] ( …