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Intermolecular clamping by hydrogen bonds: 2-pyridone⋅NH3.
Blaser S, Ottiger P, Lobsiger S, Frey HM, Leutwyler S. Blaser S, et al. Among authors: lobsiger s. Chemphyschem. 2011 Jul 11;12(10):1841-50. doi: 10.1002/cphc.201100037. Epub 2011 May 23. Chemphyschem. 2011. PMID: 21608099
S0 and S1 state structure, methyl torsional barrier heights, and fast intersystem crossing dynamics of 5-methyl-2-hydroxypyrimidine.
Lobsiger S, Frey HM, Leutwyler S, Morgan P, Pratt D. Lobsiger S, et al. J Phys Chem A. 2011 Nov 24;115(46):13281-90. doi: 10.1021/jp207213c. Epub 2011 Oct 24. J Phys Chem A. 2011. PMID: 22023157
Combining these measurements with the previous observation of efficient intersystem crossing (ISC) from the S1 state to a long-lived T1 (3npi*) state that lies ~2200 cm(-1) below [S. Lobsiger, S. et al. Phys. Chem. Chem. Phys. 2010, 12, 5032] implies that the …
Combining these measurements with the previous observation of efficient intersystem crossing (ISC) from the S1 state to a long-lived T1 (3np …
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