S0 and S1 state structure, methyl torsional barrier heights, and fast intersystem crossing dynamics of 5-methyl-2-hydroxypyrimidine.
Lobsiger S, Frey HM, Leutwyler S, Morgan P, Pratt D.
Lobsiger S, et al.
J Phys Chem A. 2011 Nov 24;115(46):13281-90. doi: 10.1021/jp207213c. Epub 2011 Oct 24.
J Phys Chem A. 2011.
PMID: 22023157
Combining these measurements with the previous observation of efficient intersystem crossing (ISC) from the S1 state to a long-lived T1 (3npi*) state that lies ~2200 cm(-1) below [S. Lobsiger, S. et al. Phys. Chem. Chem. Phys. 2010, 12, 5032] implies that the …
Combining these measurements with the previous observation of efficient intersystem crossing (ISC) from the S1 state to a long-lived T1 (3np …